ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives 2-Methyl-3-nitroaniline

2-Methyl-3-nitroaniline

2-Methyl-3-nitroaniline Basic information
Product Name:2-Methyl-3-nitroaniline
Synonyms:3-NITRO-O-TOLUIDINE;ORTHO-TOLUIDINE,3-NITRO-;3-NITRO-ORTHO-TOLUIDINE;2-methyl-3-nitro-benzenamin;3-nitro-o-toluidin;2-METHYL-3-NITROANILINE / 2-AMINO-6-NITROTOLUENE;3-Nitro-o-toluidine (NH2=1);2-methyl-3-nitrobenzenamine
CAS:603-83-8
MF:C7H8N2O2
MW:152.15
EINECS:210-059-6
Product Categories:Intermediates of Dyes and Pigments;Benzene derivatives;Drug Intermediates;API intermediates;Anilines, Aromatic Amines and Nitro Compounds;1
Mol File:603-83-8.mol
2-Methyl-3-nitroaniline Structure
2-Methyl-3-nitroaniline Chemical Properties
Melting point 88-90 °C (lit.)
Boiling point 305 °C (lit.)
density 1.378
refractive index 1.6394 (estimate)
Fp 305°C
storage temp. Store below +30°C.
solubility <1mg/l
form Crystalline Powder
pka2.31±0.10(Predicted)
color Yellow to greenish-yellow
Water Solubility <0.1 g/100 mL at 23 ºC
BRN 388393
InChIKeyHFCFJYRLBAANKN-UHFFFAOYSA-N
CAS DataBase Reference603-83-8(CAS DataBase Reference)
NIST Chemistry Reference2-Methyl-3-nitroaniline(603-83-8)
EPA Substance Registry System2-Methyl-3-nitroaniline (603-83-8)
Safety Information
Hazard Codes T,N
Risk Statements 23/24/25-33-51/53
Safety Statements 28-36/37-45-61-28A
RIDADR UN 2660 6.1/PG 3
WGK Germany 3
RTECS XU8200000
Hazard Note Toxic
HazardClass 6.1
PackingGroup III
HS Code 29214300
MSDS Information
ProviderLanguage
2-Amino-6-nitrotoluene English
SigmaAldrich English
ACROS English
ALFA English
2-Methyl-3-nitroaniline Usage And Synthesis
Chemical PropertiesYELLOW TO GREENISH-YELLOW CRYSTALLINE POWDER
Uses2-Amino-6-nitrotoluene (2-Methyl-3-nitroaniline) has been used as a standard while evaluating the potential for degradation of nitroaromatic compounds by indigenous microorganisms.
General DescriptionYellow rhombic needles (from water) or bright yellow powder.
Air & Water Reactions2-Methyl-3-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.
Reactivity Profile2-Methyl-3-nitroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers.
Fire HazardFlash point data for 2-Methyl-3-nitroaniline are not available; however, 2-Methyl-3-nitroaniline is probably combustible.
Purification MethodsCrystallise the nitrotoluidine from EtOH or *C6H6. It is steam volatile. The acetyl derivative crystallises from aqueous EtOH and has m 164o. [Beilstein 12 I 395, 12 II 460, 12 III 1944, 2 IV 1811.]
Benzenamine,ar-methyl-ar-nitro- N-(2-chloro-5-nitrobenzylidene)-2-methyl-5-nitroaniline N-(mesitylmethylene)-2-methyl-5-nitroaniline Methyl 5-METHOXY-2-METHYL-4-NITROANILINE, TECH., 95 2-BROMO-6-METHYL-4-NITROANILINE N-[(4-chlorophenyl)methyl]-2-nitroaniline 2,4-DIMETHOXY-3-METHYL-5-NITROANILINE N-[(3-fluorophenyl)methyl]-2-nitroaniline 3,3',5,5'-Tetramethylbenzidine dihydrochloride 5-CHLORO-N-METHYL-2-NITROBENZENAMINE N-[(4-methylphenyl)methyl]-4-nitroaniline ALTRENOGEST toluidine N-(2,4-dimethoxy-3-methylbenzyl)-2-methyl-4-nitroaniline AMINO ACIDS N,N-DIMETHYL-4-NITROANILINE METHYL THIOPHENE-2-CARBOXYLATE
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