Carbonyldihydrotris(triphenylphosphine)ruthenium

Carbonyldihydrotris(triphenylphosphine)ruthenium Basic information
Reaction
Product Name:Carbonyldihydrotris(triphenylphosphine)ruthenium
Synonyms:RUTHENIUM DIHYDRIDO CARBONYL TRIS (TRIPHENYLPHOSPHINE);CARBONYLDIHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II);CARBONYL(DIHYDRIDO)TRIS(TRIPHENYLPHOSPINERUTHENIUM(II));CARBONYLDIHYDRIDO TRIS(TRIPHONYLPHOSPHANE)RUTHENIUM(II);Dihydridocarbonyltris(triphenylphosphine) ruthenium;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II),99%;Carbonyl(dihydrido)tris(triphenyl phosphine)ruthenium;Dihydridocarbonyltris-(triphenylphosphino)-ruthenium
CAS:25360-32-1
MF:C55H45OP3Ru
MW:915.94
EINECS:
Product Categories:chemical reaction,pharm,electronic,materials;Ru;Metal Compounds;Catalysis and Inorganic Chemistry;Ru Catalysts;metal carbonyl complexes;Classes of Metal Compounds;Ru (Ruthenium) Compounds;Transition Metal Compounds;Ruthenium
Mol File:25360-32-1.mol
Carbonyldihydrotris(triphenylphosphine)ruthenium Structure
Carbonyldihydrotris(triphenylphosphine)ruthenium Chemical Properties
Melting point 161-163 °C(lit.)
storage temp. Inert atmosphere,2-8°C
form Powder
color white to off-white
Water Solubility Insoluble in water.
Sensitive Moisture Sensitive
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36
RIDADR UN2813
WGK Germany 3
HazardClass 4.3
PackingGroup III
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Carbonyldihydrotris(triphenylphosphine)ruthenium Usage And Synthesis
Reaction
  1. Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.
  2. Catalytic C-C bond formation.
  3. Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.
  4. Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.
  5. Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.
  6. Precatalyst for hydrogen production by means of alcohol dehydrogenation. 
Reactions of 25360-32-1
Chemical PropertiesWhite to off-white powder
Uses• Catalyst for conversion of 1,4-alkynediols into pyrroles • Catalyst for oxidation of primary alcohols to methyl esters • Catalyst for rearrangement of oximes to amides • Catalyst for C-C coupling via directed C-H activation • Cata
UsesCarbonyldihydrotris(triphenylphosphine)ruthenium(II) is a catalyst used in the preparation of ruthenium (diphenylphosphino)ethyl)amine complexes pre-catalysts for hydrogenation and dehydrogenation.
Uses
  • Catalyst for conversion of 1,4-alkynediols into pyrroles
  • Catalyst for oxidation of primary alcohols to methyl esters
  • Catalyst for rearrangement of oximes to amides
  • Catalyst for C-C coupling via directed C-H activation
  • Catalyst for enyne cyclization
Carbonyldihydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials
BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE Tetrakis(triphenylphosphine)nickel Tris(triphenylphosphine)ruthenium(II) chloride DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Bis(benzonitrile)palladium chloride CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL SULFIDE Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chloro(1,5-cyclooctadiene)rhodium(I) dimer 1,1'-Carbonyldiimidazole Tris(triphenylphosphine)rhodiu Carbonyl iron powder TRIPHENYLPHOSPHINE Carbonyldihydrotris(triphenylphosphine)ruthenium Ruthenium (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Triphenylphosphine RUTHENIUM CARBONYL

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