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| | 1-Chloro-N,N,2-trimethylpropenylamine Basic information |
| Product Name: | 1-Chloro-N,N,2-trimethylpropenylamine | | Synonyms: | TETRAMETHYL-ALPHA-CHLORENAMINE;1-CHLORO-N,N,2-TRIMETHYL-1-PROPENYLAMINE;1-CHLORO-N,N,2-TRIMETHYLPROPENYLAMINE;(1-CHLORO-2-METHYLPROPENYL)DIMETHYLAMINE;1-Chloro-N,N,2-trimethylpropenylamine, 98.5+%;1-Chloro-N,N,2-trimethylpropenylamine ,98%;Ghosez′s reagent;1-Chloro-N,N,2-triMethylpropenylaMine, 98.5+% 5ML | | CAS: | 26189-59-3 | | MF: | C6H12ClN | | MW: | 133.62 | | EINECS: | | | Product Categories: | Alkenyl;Halogenated Hydrocarbons;Organic Building Blocks | | Mol File: | 26189-59-3.mol |  |
| | 1-Chloro-N,N,2-trimethylpropenylamine Chemical Properties |
| Boiling point | 129-130 °C(lit.) | | density | 1.01 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.453(lit.) | | Fp | 80 °F | | storage temp. | 2-8°C | | solubility | Chloroform (Sparingly), Methanol (Slightly) | | pka | 4.27±0.70(Predicted) | | form | Liquid | | color | Colorless to yellow | | Stability: | Hygroscopic, Moisture Sensitive, Unstable in Solution |
| Hazard Codes | C | | Risk Statements | 10-34 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | UN 2734 8/PG 1 | | WGK Germany | 3 | | HS Code | 29211990 |
| | 1-Chloro-N,N,2-trimethylpropenylamine Usage And Synthesis |
| Chemical Properties | Colorless to yellow liquid | | Uses | 1-Chloro-N,N,2-trimethyl-1-propenylamine is an acid halogenation reagent developed by Ghosez, that enables the conversion of carboxylic acids into the corresponding chlorides under strictly neutral conditions. This method was successfully used in the total synthesis of caloporoside, roseophilin, (-)-enniatin B, (±)-epimeloscine and (±)-meloscine. | | Synthesis Reference(s) | Journal of the American Chemical Society, 94, p. 2869, 1972 DOI: 10.1021/ja00763a061
Organic Syntheses, Coll. Vol. 6, p. 282, 1988
Tetrahedron Letters, 25, p. 5043, 1984 DOI: 10.1016/S0040-4039(01)91114-1 |
| | 1-Chloro-N,N,2-trimethylpropenylamine Preparation Products And Raw materials |
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