Chlorocyclohexane

Chlorocyclohexane Basic information
Product Name:Chlorocyclohexane
Synonyms:Chlorocyclohexane, typically;Chlorocyclohexane,typically;Chlorocyclohexane, 99.5%;Anti-CXCR1 (C-terminal) antibody produced in rabbit;IL8RA;3-chloro-1-cyclohexene;3-chlorocyclohexane;3-chloro-cyclohexen
CAS:542-18-7
MF:C6H11Cl
MW:118.6
EINECS:208-806-6
Product Categories:Alkyl;Building Blocks;CHLORO ALKANE COMPOUNDS;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;542-18-7
Mol File:542-18-7.mol
Chlorocyclohexane Structure
Chlorocyclohexane Chemical Properties
Melting point -44 °C (lit.)
Boiling point 142 °C (lit.)
density 1 g/mL at 25 °C (lit.)
vapor pressure 7 hPa (20 °C)
refractive index n20/D 1.462(lit.)
Fp 84 °F
storage temp. Store below +30°C.
solubility 0.40g/l
form Liquid
color Clear
explosive limit1.1-7.5%(V)
Water Solubility 0.02 g/L (20 ºC)
Merck 14,2732
BRN 1900796
InChIKeyUNFUYWDGSFDHCW-UHFFFAOYSA-N
CAS DataBase Reference542-18-7(CAS DataBase Reference)
NIST Chemistry ReferenceCyclohexane, chloro-(542-18-7)
EPA Substance Registry SystemCyclohexane, chloro- (542-18-7)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 10-36/37/38-20
Safety Statements 26-36-37/39-16
RIDADR UN 1993 3/PG 3
WGK Germany 1
RTECS GU8685000
Autoignition Temperature290 °C
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29035990
Hazardous Substances Data542-18-7(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 3000 mg/kg
MSDS Information
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Chlorocyclohexane English
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Chlorocyclohexane Usage And Synthesis
Chemical Propertiesclear liquid
UsesChlorocyclohexane is used as the raw material in synthesis agrochemical and medicine chemical engineering products.
DefinitionChEBI: A chlorocyclohexane carrying a single chloro group.
Synthesis Reference(s)Journal of the American Chemical Society, 101, p. 3060, 1979 DOI: 10.1021/ja00505a038
Journal of the American Chemical Society, 97, p. 2281, 1975 DOI: 10.1021/ja00841a054
Tetrahedron, 44, p. 2785, 1988 DOI: 10.1016/S0040-4020(88)90014-2
Purification MethodsWash chlorocyclohexane several times with dilute NaHCO3, then repeatedly with distilled water. Dry it with CaCl2 and fractionally distil it slowly at atmospheric pressure or better under vacuum. [Perlman et al. J Org Chem 1 294 1937, IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 H 21, 5 I 8, 5 II 11, 5 III 37, 5 IV 48.]
Methylene Chloride Bromocyclohexane Calcium chloride Sodium chloride Cyclohexane Chlorocyclohexane Ferric chloride Choline chloride (-)-MENTHYL CHLORIDE Sulfuryl chloride Ammonium chloride 2-Chlorocyclohexanone Methylcyclohexane Polyvinyl chloride Potassium chloride Cyclohexene oxide Ethylcyclohexane 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile

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