2,4-Dihydroxybenzoic acid

2,4-Dihydroxybenzoic acid Basic information
Uses Toxicity Usage limits Chemical properties Application Preparation
Product Name:2,4-Dihydroxybenzoic acid
Synonyms:2,4-Dihydrox;Sodium aminosalicylate Impurity 3;2,4-Dihydroxybenzoesure;p-hydroxysalicylicacid;Resorcylic acid, beta;-Resorcylicacid;2,4-DIHYDROXYBENZOIC ACID / BETA-RESORCYLIC ACID;SS-RESORCYLIC ACID
CAS:89-86-1
MF:C7H6O4
MW:154.12
EINECS:201-946-9
Product Categories:Pyridines ,Halogenated Heterocycles ,Heterocyclic Acids;sy;Building Blocks;C7;Carbonyl Compounds;Carboxylic Acids;Intermediates of Dyes and Pigments;FINE Chemical & INTERMEDIATES;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;BenzoicAcidDerivative;Organic acids;Chemical Synthesis;Organic Building Blocks;89-86-1
Mol File:89-86-1.mol
2,4-Dihydroxybenzoic acid Structure
2,4-Dihydroxybenzoic acid Chemical Properties
Melting point 208-211 °C (dec.) (lit.)
Boiling point 237.46°C (rough estimate)
density 1.3725 (rough estimate)
vapor pressure 0Pa at 25℃
FEMA 3798 | 2,4-DIHYDROXYBENZOIC ACID
refractive index 1.6710 (estimate)
Fp 200 °C
storage temp. Inert atmosphere,Room Temperature
solubility 8g/l
form Crystalline Powder
pka3.11, 8.55, 14.0(at 25℃)
color Cream to slightly beige or pink
Odorat 100.00?%. mild phenolic
Water Solubility 8 g/L (20 ºC)
Merck 14,8157
JECFA Number908
BRN 1946213
InChIKeyUIAFKZKHHVMJGS-UHFFFAOYSA-N
LogP0.98 at 23℃ and pH3.5
CAS DataBase Reference89-86-1(CAS DataBase Reference)
NIST Chemistry Reference2,4-Dihydroxybenzoic acid(89-86-1)
EPA Substance Registry System2,4-Resorcylic acid (89-86-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 1
RTECS VH3708050
TSCA Yes
HS Code 29182990
MSDS Information
ProviderLanguage
beta-Resorcylic acid English
SigmaAldrich English
ACROS English
ALFA English
2,4-Dihydroxybenzoic acid Usage And Synthesis
Uses2,4-Dihydroxybenzoic acid is a useful synthetic intermediate. An organic building block for plastics and rubber products.
ToxicityGRAS (FEMA).
Usage limitsFEMA (mg/kg): cold drink: 450; Meat, dairy, processed vegetables, 100; fudge, gel, pudding, snack food, beverages, breakfast cereals, fats, cheeses, poultry products, fish, spices, sweet sauce, dairy products, meat soup, fruit ice Egg products, jams, jelly, rehydrated vegetables, 500; soup: 250; jelly sugar: 3333; instant coffee and tea: 12.5; sugar substitute: 12500; seasoning spices: 25000.
Chemical propertiesIt appears as white needle crystal. It will contain crystal water upon crystallization from the water. It appears as an anhydride at 100 ℃. Melting point 218-219 ° C (it has a melting point of 213 ° C upon thermal shock). Soluble in hot water, ethanol, ether. Cooking in water, acid or salt solution will remove carbon dioxide. It exhibits red color upon reaction with ferric chloride.
Application
  • The product has the chemical properties of both resorcinol and salicylic acid. It can be used in chemical reagents for colorimetric determination of iron, titanium and other elements; for organic synthesis, it is mainly used for dyes and pharmaceutical intermediates. 2, 4-dihydroxybenzoic acid is a major raw material during the production of acidic medicated pink 3BM, which consumes 157 kg per ton of dye (by 100%).
  • Used as a dye intermediate, medicine and reagents
  • Used as dyes, pharmaceuticals, pesticide intermediates
PreparationIt is derived from the hydroxylation of resorcinol.
Chemical Propertiescream to slightly beige or pink crystalline powder
Chemical PropertiesDihydroxybenzoic acid is a colorless solid and is used as a flavor modifier.
OccurrenceReported present in avocados, beer, red wine, roast coffee, sherry, smoked sausage and white wine
Uses2,4-Dihydroxybenzoic acid is used in Intermediates, Plasticizers, Plastic and Rubber Products, a organic building block.
UsesIntermediate for dyestuffs and drugs; spot test reagent for iron.
PreparationPrepared from resorcinol and potassium bicarbonate in glycerol or water by heating and passing carbon dioxide through the mixture.
Purification MethodsCrystallise the acid from water. [Beilstein 10 IV 1420.]
Methylparaben 4-Hydroxybenzoic acid Salicylic acid Ethyl 2-(Chlorosulfonyl)acetate 2'-Hydroxy-3-phenylpropiophenone Ascoric Acid Protocatechuic acid 2,3-DIHYDROXYBENZOIC ACID,DIHYDROXYBENZOIC ACID, 2,3- 3-Hydroxybenzoic acid Folic acid Glycine Methyl 3,4-dihydroxybenzoate Butylparaben 2,5-DIHYDROXYBENZOIC ACID 2,3,4-Trihydroxybenzoic acid 3,5-DIHYDROXYBENZOIC ACID 2,6-DIHYDROXYBENZOIC ACID Citric acid

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.