ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Asparagine derivatives D-(-)-Asparagine monohydrate

D-(-)-Asparagine monohydrate

D-(-)-Asparagine monohydrate Basic information
Product Name:D-(-)-Asparagine monohydrate
Synonyms:ASPARAGINE, D-;ASPARAGINE;(D)-ASPARTIC ACID 4-AMIDE;D-ASPARAGINE;(R)-2-AMINOSUCCINIC ACID 4-AMIDE;(R)-2-Aminosuccinamic acid;H-D-Asn-OH·H2O;D-2-Aminosuccinamic acid
CAS:2058-58-4
MF:C4H8N2O3
MW:132.12
EINECS:218-163-3
Product Categories:Amino Acids and Derivatives;Amino Acids;Amino Acids Derivatives
Mol File:2058-58-4.mol
D-(-)-Asparagine monohydrate Structure
D-(-)-Asparagine monohydrate Chemical Properties
Melting point 280 °C (dec.) (lit.)
alpha -35 º (c=5, 5M HCl)
Boiling point 438.0±40.0 °C(Predicted)
density 1.404±0.06 g/cm3(Predicted)
storage temp. Store at 0-5°C
solubility Aqueous Acid (Sparingly), Water (Slightly, Sonicated)
pka2.17(at 20℃)
form Solid
color White to Off-White
optical activity[α]20/D 35°, c = 5 in 5 M HCl
Merck 13,842
BRN 1723526
Stability:Hygroscopic
InChIKeyDCXYFEDJOCDNAF-UWTATZPHSA-N
LogP-1.880 (est)
CAS DataBase Reference2058-58-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
WGK Germany 1
HS Code 29241900
MSDS Information
ProviderLanguage
D-Aspartic acid 4-amide monohydrate English
SigmaAldrich English
D-(-)-Asparagine monohydrate Usage And Synthesis
Chemical Propertiescrystalline powder
UsesD-Asparagine is an isomer of L-Asparagine (A790005) and is used by bacteria (such as Saccharomyces cerevisiae) as a sole nitrogen source for replication. L-Asparagine is also a competitive inhibitor of staphylococcal L-asparaginase and is used as a reagent to synthesize peptide antibiotics.
DefinitionChEBI: An optically active form of asparagine having D-configuration.
Synthesis Reference(s)Chemical and Pharmaceutical Bulletin, 35, p. 2994, 1987 DOI: 10.1248/cpb.35.2994
D-(-)-Asparagine monohydrate Preparation Products And Raw materials
Raw materialsDL-Asparagine monohydrate
RINK AMIDE RESIN MELIBIOSE ASPARAGINASE N-(9-Fluorenylmethyloxycarbonyl)-N'-trityl-D-asparagine 4-[(2,4-Dimethoxyphenyl)(Fmoc-amino)methyl]phenoxyacetic acid p-Toluenesulfonic acid monohydrate Ascoric Acid Citric acid monohydrate Boc-D-Asparagine N-Carbobenzyloxy-D-asparagine L-Asparagine D-(-)-Asparagine monohydrate L-ASPARTIC ACID BOC-D-ASN-ONP FMOC-ASN(TRT)-OPFP Fomesafen DIMETHYL 5-(2-([3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]AMINO)ETHYL)-4,6-DIOXOTETRAHYDRO-2H-PYRROLO[3,4-D]ISOXAZOLE-3,3(3AH)-DICARBOXYLATE Citric acid
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