(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Basic information
Uses
Product Name:(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
Synonyms:(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE;(R)-1-{(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclo;(R)-(-)-1-{(S)-2-[Bis(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine,min.97%;(r,r)-1-[1-(dicyclohexylphosphino)ethyl]-2-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (acc to cas);(R)-1-{(S)-2-[Bis(4-Methoxy-3,5-diMeth;(R)-(-)-1-{(S)-2-[Bis(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine, min. 97%;(R)-(-)-1-{(S)-2-[Bis(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocenyl}
ethyldicyclohexylphosphine, min. 97%
;(R)-(-)-1-{(S)-2-[Bis(3,5-diMethyl-4-Methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine
CAS:360048-63-1
MF:C42H50FeO2P2
MW:704.65
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;organophosphine ligand;Josiphos Series
Mol File:360048-63-1.mol
(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Structure
(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Chemical Properties
alpha -270° ±10° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Usage And Synthesis
Uses
  1. Homogeneous chiral nickel-catalyzed asymmetric hydrogenation of substituted aromatic α-aminoketone hydrochlorides through dynamic kinetic resolution.
  2. Pd/Josiphos-catalyzed enantioselective α-arylation of silyl ketene acetals.
  3. Ligand used in the cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstitued allenes.
addition of silylacetylenes to 1,1-disubstitued allenes
Chemical Properties(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE is Orange powder
General Descriptionsold in collaboration with Solvias AG
(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Preparation Products And Raw materials
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(S)-2-(DI-TERT.-BUTYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE (R)-(S)-JOSIPHOS (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(+)-1-((R)-2-(Diphenylphosphino)ferrocenyl)ethyldicyclohexylphosphine BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

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