Methyl 3-chlorobenzoate

Methyl 3-chlorobenzoate Basic information

Product Name:	Methyl 3-chlorobenzoate
Synonyms:	3-chloro-benzoicacimethylester;Benzoic acid, 3-chloro-, methyl ester;Benzoic acid, m-chloro-, methyl ester;benzoicacid,3-chloro-,methylester;m-chloro-benzoicacimethylester;M-CHLOROBENZOIC ACID METHYL ESTER;METHYL 3-CHLOROBENZOATE;METHYL M-CHLOROBENZOATE
CAS:	2905-65-9
MF:	C8H7ClO2
MW:	170.59
EINECS:	220-814-1
Product Categories:	Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Aromatic Esters;C8 to C9;Carbonyl Compounds;Esters
Mol File:	2905-65-9.mol

Methyl 3-chlorobenzoate Chemical Properties

Melting point	21 °C (lit.)
Boiling point	99-101 °C/12 mmHg (lit.)
density	1.227 g/mL at 25 °C (lit.)
refractive index	n20/D 1.531(lit.)
Fp	220 °F
storage temp.	Sealed in dry,Room Temperature
form	Liquid or Low Melting Solid
color	Clear colorless to yellow
Merck	14,2123
BRN	2045126
CAS DataBase Reference	2905-65-9(CAS DataBase Reference)
NIST Chemistry Reference	3-Cl-C6H4-COOCH3(2905-65-9)
EPA Substance Registry System	Methyl m-chlorobenzoate (2905-65-9)

Safety Information

Safety Statements	24/25
WGK Germany	3
TSCA	Yes
HS Code	29163990
Hazardous Substances Data	2905-65-9(Hazardous Substances Data)

MSDS Information

Provider	Language
3-Chlorobenzoic acid methyl ester	English
SigmaAldrich	English
ACROS	English
ALFA	English

Methyl 3-chlorobenzoate Usage And Synthesis

Chemical Properties	CLEAR COLORLESS TO YELLOW LIQUID
General Description	The (1+1) Resonance Enhanced Multiphoton Ionisation (REMPI) spectrum and the fluorescence excitation spectrum of methyl 3-chlorobenzoate has been measured in the supersonic free jet. Reaction of methyl 3-chlorobenzoate with lithium diisobutyl-t-butoxyaluminum hydride (LDBBA) has been investigated.

Methyl 3-chlorobenzoate Preparation Products And Raw materials

Raw materials	Benzoic acid, 3-chloro-, 2-propen-1-yl ester-->4-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL) CHLOROBENZENE-->2-ALLYLOXYPYRIDINE-->3-Chlorobenzyl alcohol-->1-Chloro-3-iodobenzene-->Methanol
Preparation Products	Bifenox-->Dimethyl isophthalate-->Methyl 5-chloro-2-nitrobenzoate-->Methyl 3-(4-Methylphenyl)benzoate-->3-Chloro-5-methoxycarbonyl-phenyl-boronic acid pinacol ester

Dacthal Methyl CHROMIUM, TRICARBONYL[(1,2,3,4,5,6-ETA)-METHYL 2-CHLOROBENZOATE]- 6-CHLOROISATIN METHYL 2-CHLOROBENZOATE, 98+%,Methyl 2-chlorobenzoate 99+%,METHYL O-CHLOROBENZOATE,METHYL 2-CHLOROBENZOATE (4,5-DICHLORO-1H-IMIDAZOL-1-YL)METHYL 4-CHLOROBENZOATE METHYL 2-CHLOROBENZOATE, (2-CHLOROBENZOIC ACID METHYL ESTER) OXALIC ACID BIS[2,4,5-TRICHLORO-6-(PENTYLOXYCARBONYL)PHENYL] ESTER CHROMIUM, TRICARBONYL[(1,2,3,4,5,6-ETA)-METHYL 3-CHLOROBENZOATE]- Methyl 3-chlorobenzoate Methyl 5-chloroanthranilate METHYL 4-CHLOROBENZOATE, (4-CHLOROBENZOIC ACID METHYL ESTER) (4-chlorophenyl)methyl 4-chlorobenzoate (4,5-DICHLORO-1H-IMIDAZOL-1-YL)METHYL 4-CHLOROBENZOATE, TECH CHROMIUM, TRICARBONYL[(1,2,3,4,5,6-ETA)-METHYL 4-CHLOROBENZOATE]- ROSE BENGAL LACTONE METHYL P-CHLOROBENZOATE,METHYL 4-CHLOROBENZOATE METHYL 3-CHLOROBENZOATE, (3-CHLOROBENZOIC ACID METHYL ESTER

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