ChemicalBook Product Catalog Pharmaceutical intermediates Heterocyclic compound Pyridine compound Bromopyridine 2-Bromopyridine-5-boronic acid

2-Bromopyridine-5-boronic acid

2-Bromopyridine-5-boronic acid Basic information
Product Name:2-Bromopyridine-5-boronic acid
Synonyms:6-BROMOPYRIDINE-3-BORONIC ACID;6-BROMOPYRIDIN-3-YL-3-BORONIC ACID;(6-BROMOPYRIDIN-3-YL)BORONIC ACID;6-BROMO-3-PYRIDINEBORONIC ACID;(6-BROMO-3-PYRIDINYL)-BORONIC ACID;AKOS BRN-0200;RARECHEM AK ML 0443;6-BROMOPYRIDIN-3-LBORONIC ACID
CAS:223463-14-7
MF:C5H5BBrNO2
MW:201.81
EINECS:672-028-7
Product Categories:alkyl bromide|boric acid;Boronic acid;Organoborons;B (Classes of Boron Compounds);Bromopyridines;Halopyridines;blocks;BoronicAcids;Pyridine;Boronic acids;Boronic Acids & Esters;Boronic Acids;Boronic Acids and Derivatives;Heteroaryl;Boronic Acids & Esters;Pyridines
Mol File:223463-14-7.mol
2-Bromopyridine-5-boronic acid Structure
2-Bromopyridine-5-boronic acid Chemical Properties
Melting point 161-166 °C
Boiling point 358.2±52.0 °C(Predicted)
density 1.78±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility soluble in Methanol
pka6.62±0.10(Predicted)
form solid
color white to off-white
BRN 9119918
CAS DataBase Reference223463-14-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39
RIDADR 2811
WGK Germany 3
TSCA No
HazardClass IRRITANT
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-Bromopyridine-5-boronic acid Usage And Synthesis
Chemical PropertiesOff-white solid
UsesReactant involved in:
  • Iterative cross-coupling reactions for synthesis of non-cytotoxic terpyridines
  • The Garlanding approach for synthesis of phenyl-pyridyl scaffolds
  • Cyanation for synthesis of aromatic nitriles
  • Suzuki-Miyaura cross-coupling with dihalopyridines and dihalobipyridines
  • Petasis boronic Mannich reaction
General DescriptionMay contain varying amounts of anhydride
2-Bromopyridine-5-boronic acid Preparation Products And Raw materials
Raw materialsDiethyl ether-->n-Butyllithium-->Triisopropyl borate-->2,5-Dibromopyridine
Preparation Products2-Bromo-5-iodopyridine-->2-Bromo-5-hydroxypyridine
1-Hexadecylpyridinium bromide 6-BROMOPYRIDINE-3-BORONIC ACID, PINACOL ESTER,2-BROMOPYRIDINE-5-BORONIC ACID PINACOL ESTER,2-BROMOPYRIDINE-5-BORONIC ACID PINACOLATE 2-BROMO-3-METHYLPYRIDINE-5-BORONIC ACID 2-Chloro-3-hydroxypyridine BORONIC ACID, (6-BROMO-2-FLUORO-3-PYRIDINYL)- Ascoric Acid 2-Bromopyridine Zinc borate 2-Bromopyridine-5-boronic acid 3-Aminopyridine 2,2'-Bipyridine 2-Bromo-5-nitropyridine Chromium picolinate 2,6-Lutidine 3-Hydroxypyridine 2-BROMO-3-METHYLPYRIDINE-5-BORONIC ACID PINACOL ESTER 6-BROMO-2,4-DIMETHYLPYRIDIN-3-YLBORONIC ACID EPA
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