4-Chloro-1,3-benzenediamine

4-Chloro-1,3-benzenediamine Basic information
Product Name:4-Chloro-1,3-benzenediamine
Synonyms:1,3-benzenediamine,-chloro-;1-Chloro-2,4-Diaminobenzene;4-Chloro-1,3-benzenediamine;4-chloro-3-benzenediamine;4-Chloro-meta-phenylenediamine;4-chloro-m-phenylenediamin;4-Chlorophene-1,3-diamine;4-Chlorophenylene-1,3-diamine
CAS:5131-60-2
MF:C6H7ClN2
MW:142.59
EINECS:225-877-9
Product Categories:
Mol File:5131-60-2.mol
4-Chloro-1,3-benzenediamine Structure
4-Chloro-1,3-benzenediamine Chemical Properties
Melting point 87-90 °C (lit.)
Boiling point 232.49°C (rough estimate)
density 1.2124 (rough estimate)
refractive index 1.5210 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka3.95±0.10(Predicted)
form powder to crystal
color White to Gray to Brown
Water Solubility <0.1 g/100 mL at 19 ºC
CAS DataBase Reference5131-60-2(CAS DataBase Reference)
IARC3 (Vol. 27, Sup 7) 1987
NIST Chemistry Reference1,3-Benzenediamine, 4-chloro-(5131-60-2)
EPA Substance Registry System4-Chloro-m-p.henylenediamine (5131-60-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 1673 6.1/PG 3
WGK Germany 3
RTECS SS8800000
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29215900
Hazardous Substances Data5131-60-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
4-Chloro-1,3-phenylenediamine English
SigmaAldrich English
ALFA English
4-Chloro-1,3-benzenediamine Usage And Synthesis
Chemical PropertiesCrystals. Soluble in ethanol; slightly soluble in water; insoluble in petroleum ether.
UsesThis compound has uses in dye production and in rubber processing.
Uses4-Chloro-1,3-diaminobenzene has been used to study the mutagenic effect of phenylenediamines hair chemicals on Salmonella typhimurium TA 102.
DefinitionChEBI: 4-Chloro-meta-phenylenediamine is a member of monochlorobenzenes.
General DescriptionGray powder or dark purple solid.
Air & Water Reactions4-Chloro-1,3-benzenediamine is sensitive to prolonged exposure to light and air. Insoluble in water.
Reactivity ProfileAmines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
Health HazardACUTE/CHRONIC HAZARDS: 4-Chloro-1,3-benzenediamine is a positive animal carcinogen and suspected human carcinogen.
Fire HazardFlash point data for 4-Chloro-1,3-benzenediamine are not available; however, 4-Chloro-1,3-benzenediamine is probably combustible.
Safety ProfileSuspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl and NOx. See also AROMATIC AMINES.
4-Chloro-1,3-benzenediamine Preparation Products And Raw materials
Preparation ProductsChromate(3-), bis[3-[[2-(amino-κN)-4-amino-5-chlorophenyl]azo-κN1]-2-(hydroxy-κO)-5-nitrobenzenesulfonato(3-)]-, disodium hydrogen-->Direct Black 11-->MORDANT BROWN 48-->N-(3-Amino-4-chlorophenyl)-2,2-dimethylpropanamide
4-CHLORO-5-NITRO-2-TOLUIDINE 2-Chloro-3,5-dinitrobenzoic acid 1,3-Dichloro-4,6-dinitrobenzene 1,3-Phenylenediamine sulfate 2,4,6-TRINITRO-1-CHLOROBENZENE 2-Chloro-5-nitro-benzamine Benzene-1,3-diamine dihydrochloride 1,3-DICHLORO-2,4,6-TRINITROBENZENE 1,3,5-trichloro-2,4-dinitrobenzene N1-(6-CHLORO-2-METHYL-3-NITROPHENYL)ACETAMIDE 2,4-DICHLORO-3,5-DINITROBENZONITRILE 4-Chloro-3-nitroaniline 2-Chloro-3,5-dinitrobenzotrifluoride 2-CHLORO-5-NITRO-N-HYDROXYETHYL P-PHENYLENEDIAMINE 2,4-Dinitrochlorobenzene 2,4-DINITROCHLOROBENZENE-6-SULFONIC ACID p-Phenylenediamine o-Phenylenediamine

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