(S)-1-Bromo-2-methylbutane

(S)-1-Bromo-2-methylbutane Basic information
Product Name:(S)-1-Bromo-2-methylbutane
Synonyms:(2S)-1-BROMO-2-METHYL-BUTANE;(S)-(+)-1-BROMO-2-METHYLBUTANE;(S)(+)-2-METHYLBUTYLBROMIDE;(+)-2-Methyl-1-bromobutane;(S)-(+)-2-Methyl-1-bromobutane;(S)-2-Methyl-1-bromobutane;(s)-butan;1-Brom-2-methylbutan(S)-
CAS:534-00-9
MF:C5H11Br
MW:151.04
EINECS:208-583-5
Product Categories:
Mol File:534-00-9.mol
(S)-1-Bromo-2-methylbutane Structure
(S)-1-Bromo-2-methylbutane Chemical Properties
Melting point -105.4°C (estimate)
alpha 4.5 º (c=5 in chloroform)
Boiling point 121-122 °C(lit.)
density 1.223 g/mL at 25 °C(lit.)
refractive index n20/D 1.445(lit.)
Fp 72 °F
solubility soluble in Acetone, Chloroform, Dichloromethane, Diethyl Ether
form Oil
color Colorless
optical activity[α]21/D +4.5°, c = 5 in chloroform
Water Solubility Insoluble in water.
Sensitive Light Sensitive
Merck 13,605
BRN 1718815
CAS DataBase Reference534-00-9(CAS DataBase Reference)
NIST Chemistry ReferenceButane, 1-bromo-2-methyl-, (S)-(534-00-9)
EPA Substance Registry SystemButane, 1-bromo-2-methyl-, (2S)- (534-00-9)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36
RIDADR UN 1993 3/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
(2S)-1-Bromo-2-methylbutane English
SigmaAldrich English
(S)-1-Bromo-2-methylbutane Usage And Synthesis
Uses(S)-(+)-1-Bromo-2-methylbutane, is used for the synthesis of chiral nematic liquid crystals and optically active Grignard reagents.
Purification MethodsWash the bromobutane with ice-cold H2O, dry by freezing, shake it twice with an equal volume of H2SO4 at 0o, and twice with an equal volume of H2O at 0o. Freeze-dry and keep over freshly heated (and then cooled) K2CO3, and distil it
(S)-1-Bromo-2-methylbutane Preparation Products And Raw materials
Preparation Products(S)-(+)-5-METHYL-1-HEPTANOL-->DIETHYL METHYL(2-METHYLBUTYL)MALONATE-->4-[(2S)-2-Methylbutyl]-1,1'-biphenyl
EXO-2-BROMO-5,5-ETHYLENEDIOXYBICYCLO[2.2.1]HEPTANE-SYN-7-CARBOXYLIC ACID STIGMASTERYL ACETATE DIBROMIDE BORNYL BROMIDE EXO-2-BROMO-5-OXO-BICYCLO[2.2.1]HEPTANE-SYN-7-CARBOXYLIC ACID S-(-)-3-Bromocamphor 2,3-dibromo-2-methylbutane 1-Bromo-2-methylbutane 3,9,10-TRIBROMO-(-)-CAMPHOR 2,3,5,5-TETRABROMO-4,4-DIMETHYLCYCLOPENT-2-EN-1-ONE 2-BROMO-2-METHYLBUTANE 3-BROMO-7-(BROMOMETHYL)-1,7-DIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE (2-BROMO-CYCLOHEXYL)-ACETIC ACID METHYL ESTER D-3-BROMOCAMPHOR 2-BROMO-3-METHYLBUTANE 2-BROMO-2-ETHYLBUTYRYL BROMIDE 2-Bromo-2-methylpropane (+)-Camphor Bromide 2-BROMO-3,3,6,8-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALEN-1-ONE

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