ALUMINUM CITRATE

ALUMINUM CITRATE Basic information
Description Synthesis Application Toxicological studies Reference
Product Name:ALUMINUM CITRATE
Synonyms:aluminiumcitrate;Aluminum2-hydroxy-1,2,3-propanetricarboxylate;Citricacid,aluminumsalt;ALUMINUM CITRATE;Alminium citrate;Einecs 250-484-4;Aluminum citrate ,96%;1,2,3-Propanetricarboxylicacid, 2-hydroxy-, aluminum salt (1:)
CAS:31142-56-0
MF:C6H11AlO7
MW:222.13
EINECS:250-484-4
Product Categories:Organic-metal salt
Mol File:31142-56-0.mol
ALUMINUM CITRATE Structure
ALUMINUM CITRATE Chemical Properties
Water Solubility dissolves slowly in cold H2O, soluble hot H2O, ammonia [MER06]
Safety Information
Hazard Codes Xn
Risk Statements 22-36/38-48/22
Safety Statements 26
MSDS Information
ALUMINUM CITRATE Usage And Synthesis
DescriptionAluminum citrate is a chemical compound formed by the reaction between aluminum salt and citric acid.
SynthesisAluminum citrate can be manufactured with aluminum chloride and citric acid as the starting materials. The pH of the mixture can be adjusted with either ammonium hydroxide or sodium hydroxide to obtain aluminum citrate.1,2
ApplicationAluminum citrate solutions can be used for crosslinking polymers such as carboxymethylcellulose (CMC) or partially hydrolyzed polyacrylamide. This crosslinking with aluminum citrate is applied in enhanced oil recovery processes. The in situ gelling of the polymers results in blocking of highly permeable zones, providing the possibility to recover oils which otherwise could not be recovered by conventional methods.3 Crosslinked polymeric materials by aluminum citrate are used in subterranean formations to reduce the permeability of the formations to water.1 Aluminum citrate has been used as precursor to synthesize aluminum nitride.4 Aluminum citrate has been used in cosmetic products with anti-perspiration effect.5
Toxicological studiesAluminum is established as neurotoxicant. The uptake of aluminum in the form of aluminum citrate is 50 times than that in aluminum hydroxide form.6
Reference
  1. Julie E. Smith, Aluminum citrate preparations and methods, Patent US5559263A
  2. Philip W. Staal, Method for the preparation of liquid aluminum citrate, Patent US4447364A
  3. Lawrence M. Fodor, R. Lynn Cobb, Aluminum citrate solution, Patent US4601340A
  4. L. Weng, D. Huang, X. Jiang, Synthesis of aluminum nitride from aluminum citrate precursor, Materials Letters, 1993, vol. 18, pp. 159-162
  5. www.bfr.bund.de
  6. https://de.wikipedia.org/wiki/Aluminiumcitrat#cite_note-DOI10.1007/BF00817919-10
Chemical Propertieswhite powder(s) or scales; study of complex formation in [LOP84] [MER06]
ALUMINUM CITRATE Preparation Products And Raw materials
Ammonium iodide Aluminum fluoride Ammonium chloride Aluminum citrate (dibasic) 3-HYDROXY-3-METHYLGLUTARIC ACID Aluminum, citrate hydroxy complexes ALUMINUM FORMATE Citric acid, aluminium salt hydrate, 80+% ALUMINUM ETHOXIDE Aluminum diacetate hydroxide ALUMINUM CITRATE Aluminum acetate ALUMINUM FORMOACETATE ALUMINUM HYDROXIDE HYDRATE ALUMINUM ACETATE, DIBASIC Aluminum hydroxide D(+)-Malic acid 2-ETHYL-2-HYDROXYBUTYRIC ACID

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