ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Methyl ester compound Methyl 3-bromobenzoate

Methyl 3-bromobenzoate

Methyl 3-bromobenzoate Basic information
Product Name:Methyl 3-bromobenzoate
Synonyms:METHYL 3-BROMOBENZOATE FOR SYNTHESIS;3-bromo-benzoicacimethylester;Benzoic acid, m-bromo-, methyl ester;Benzoicacid,3-bromo-,methylester;m-Bromobenzoic acid methyl ester;RARECHEM AL BF 0052;3-BROMOBENZOIC ACID METHYL ESTER;Methyl 3-bromobenzoate, 98+%
CAS:618-89-3
MF:C8H7BrO2
MW:215.04
EINECS:210-569-9
Product Categories:Aromatic Esters;API intermediates;Acids & Esters;Bromine Compounds;C8 to C9;Carbonyl Compounds;Acids and Derivatives;Esters;Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:618-89-3.mol
Methyl 3-bromobenzoate Structure
Methyl 3-bromobenzoate Chemical Properties
Melting point 31-33 °C(lit.)
Boiling point 127-128 °C15 mm Hg(lit.)
density 1.5313 (rough estimate)
refractive index 1.5575
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form Crystalline Solid or Liquid
color White to light yellow
Water Solubility Slightly soluble in water.
BRN 1940810
InChIKeyKMFJVYMFCAIRAN-UHFFFAOYSA-N
CAS DataBase Reference618-89-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzoic acid, 3-bromo-, methyl ester(618-89-3)
EPA Substance Registry SystemBenzoic acid, 3-bromo-, methyl ester (618-89-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26-24/25
WGK Germany 3
TSCA Yes
HS Code 29163990
MSDS Information
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Methyl 3-bromobenzoate English
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Methyl 3-bromobenzoate Usage And Synthesis
Chemical PropertiesMethyl 3-bromobenzoate is white to light yellow low melting crystalline
UsesMethyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.
UsesMethyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.
General DescriptionMethyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.
Methyl 3-bromobenzoate Preparation Products And Raw materials
Preparation Products3-Cyclopropylbenzoic acid-->3-ETHYNYL-BENZOIC ACID METHYL ESTER-->METHYL 3-(3-OXOPROPYL)BENZOATE-->Benzoic acid, 3-ethenyl-, methyl ester-->3-Bromobenzyl alcohol-->Isophthalic acid-->[1,1'-Biphenyl]-3-carboxylic acid, 3'-chloro-, methyl ester-->METHYL 3'-NITRO[1,1'-BIPHENYL]-3-CARBOXYLATE
Methylparaben Methyl 2-bromo-2-methylpropionate METHYL 2-BROMOBENZOATE,METHYL O-BROMOBENZOATE,Methyl2-bromobenzoate,99% Methyl Bensulfuron methyl Parathion-methyl Methyl 3-bromobenzoate Methyl 4-cyanobenzoate 4-Bromomethylbenzoic acid Kresoxim-methyl Methyl bromoacetate Thiophanate-methyl Methyl benzoate Methyl acrylate Benzoic acid Methyl acetate Methyl bromide METHYL THIOPHENE-2-CARBOXYLATE
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