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BARIUM TRIFLUOROMETHANESULFONATE

BARIUM TRIFLUOROMETHANESULFONATE Basic information
Product Name:BARIUM TRIFLUOROMETHANESULFONATE
Synonyms:trifluoro-methanesulfonicacibariumsalt;barium trifluoromethanesulphonate;TRIFLUOROMETHANESULFONIC ACID BARIUM;BARIUM TRIFLUOROMETHANESULFONATE, 99% (BARIUM TRIFLATE);Trifluoromethanesulfonic acid barium salt;Barium triflate, Trifluoromethanesulfonic acid barium salt;Bis(trifluoromethanesulfonic acid)barium salt;Barium trifluoromethanesulfonate,98%
CAS:2794-60-7
MF:C2BaF6O6S2
MW:435.47
EINECS:220-526-6
Product Categories:OTf&NTf series;Other Metal;metal triflate compounds;triflate
Mol File:2794-60-7.mol
BARIUM TRIFLUOROMETHANESULFONATE Structure
BARIUM TRIFLUOROMETHANESULFONATE Chemical Properties
Melting point >300 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
color white
Water Solubility Soluble in water.
Sensitive Hygroscopic
Hydrolytic Sensitivity5: forms reversible hydrate
BRN 3729346
Exposure limitsACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
Stability:hygroscopic
EPA Substance Registry SystemMethanesulfonic acid, trifluoro-, barium salt (2794-60-7)
Safety Information
Hazard Codes Xn
Risk Statements 20/22
Safety Statements 28
RIDADR UN 1564 6.1/PG 3
WGK Germany 1
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 29049020
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BARIUM TRIFLUOROMETHANESULFONATE Usage And Synthesis
Chemical PropertiesWhite powder
UsesBa(CF3SO3) can be utilized as a precursor to synthesize:
  • Alkali metal and silver trifluoromethanesulfonates.
  • Sodium trifluoromethanesulfonate (sodium triflate) by reacting with sodium sulfate. Sodium triflate finds application in organic synthesis as an efficient catalyst as well as a reactant in catalytic asymmetric Mannich-type reactions, and Diels-Alder reactions.

BARIUM TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Preparation ProductsLithium triflate-->Potassium trifluoromethanesulfonate
Iron(III) trifluoromethanesulfonate Zinc TrifluoroMethanesulfinate INDIUM(III) TRIFLUOROMETHANESULFONATE Potassium trifluoromethanesulfonate IRON(II) TRIFLUOROMETHANESULFONATE Trimethylsilyl trifluoromethanesulfonate SILVER TRIFLUOROMETHANESULFONATE GALLIUM(III) TRIFLUOROMETHANESULFONATE Sodium trifluoromethanesulfonate MAGNESIUM TRIFLUOROMETHANESULFONATE ZINC TRIFLUOROMETHANESULFONATE CALCIUM TRIFLUOROMETHANESULFONATE COPPER(II) TRIFLUOROMETHANESULFONATE CERIUM(III) TRIFLUOROMETHANESULFONATE Lithium triflate Sodium trifluoromethanesulfinate Bismuth(III) trifluoromethanesulfonate BARIUM TRIFLUOROMETHANESULFONATE
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