3-Fluoroanisole

3-Fluoroanisole Basic information

Product Name:	3-Fluoroanisole
Synonyms:	M-FLUORO METHOXYBENZENE;M-FLUOROANISOLE;1-Fluoro-3-methoxybenzene;1-fluoro-3-methoxy-benzene;Benzene, 1-fluoro-3-methoxy-;3-Fluoroanisole,99%;3-Fluoroanisole 99%;m-Fluorophenyl methyl ether
CAS:	456-49-5
MF:	C7H7FO
MW:	126.13
EINECS:	207-267-4
Product Categories:	AnisoleSeries;Fluorobenzene;Anisoles, Alkyloxy Compounds & Phenylacetates;Fluorine Compounds;Ethers;Organic Building Blocks;Other fluorin-contained compounds;Oxygen Compounds
Mol File:	456-49-5.mol

3-Fluoroanisole Chemical Properties

Melting point	-35°C
Boiling point	158 °C/743 mmHg (lit.)
density	1.104 g/mL at 25 °C (lit.)
refractive index	n20/D 1.488(lit.)
Fp	111 °F
storage temp.	Sealed in dry,2-8°C
solubility	Chloroform, Methanol
form	Oil
Specific Gravity	1.104
color	Colourless
BRN	1858895
InChIKey	MFJNOXOAIFNSBX-UHFFFAOYSA-N
CAS DataBase Reference	456-49-5(CAS DataBase Reference)
NIST Chemistry Reference	m-Fluoroanisole(456-49-5)

Safety Information

Hazard Codes	F
Risk Statements	10
Safety Statements	16
RIDADR	UN 1993 3/PG 3
WGK Germany	3
Hazard Note	Flammable
HazardClass	3
PackingGroup	III
HS Code	29093090

MSDS Information

Provider	Language
3-Fluoroanisole	English
SigmaAldrich	English
ACROS	English
ALFA	English

3-Fluoroanisole Usage And Synthesis

Chemical Properties	clear colorless to straw yellow liquid
Uses	3-Fluoroanisole is used in the preparation of tertiary benzylic nitriles.
Uses	3-Fluoroanisole was used in the synthesis of 4-fluoro-5,6-dihydroxytryptamine. It was also used in the synthesis of 3-fluoro- and 5-fluoronoradrenaline.
Synthesis Reference(s)	Tetrahedron, 52, p. 23, 1996 DOI: 10.1016/0040-4020(95)00867-8

3-Fluoroanisole Preparation Products And Raw materials

Raw materials	3-Iodoanisole-->Anisole
Preparation Products	2-Fluoro-6-methoxybenzaldehyde-->2-Fluoro-6-hydroxyphenylboronic acid-->5-Fluoro-2-nitroanisole-->4-BROMO-3-FLUOROANISOLE-->2-FLUORO-4-METHOXYBENZYL ALCOHOL-->2-FLUORO-6-METHOXYPHENOL-->2-Bromo-3-fluoroanisole-->2-Fluoro-4-methoxybenzoic acid

3-Fluorobenzoic acid 4-Bromo-3-fluoroanisole 3,5-Difluoroanisole FENFLURAMINE FMOC-ASP(OTBU)-OPFP 2,3,5,6-TETRAFLUOROANISOLE 4-Fluoroanisole Transfluthrin 4,4'-DIMETHOXYOCTAFLUOROBIPHENYL 3-Chloroanisole Dimethoxybenzene 3-Fluoroanisole 3-Bromoanisole Anisole PENTAFLUOROPHENOXYACETIC ACID 4-Fluorobenzaldehyde Florfenicol 1,3-Difluorobenzene

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