BENZYLOXYACETALDEHYDE

BENZYLOXYACETALDEHYDE Basic information
Product Name:BENZYLOXYACETALDEHYDE
Synonyms:BENZYLOXYACETALDEHYDE;Benzyloxyacetaldehyde, stabilized, 95%;Benzyloxyacetaldehyde CAS;2-(Benzyloxy)ethanal;2-(Phenylmethoxy)acetaldehyde;a-(Benzyloxy)acetaldehyde;Benzyloxyacetaldehyde, 95%, stabilized;(Benzyloxy)ethanal
CAS:60656-87-3
MF:C9H10O2
MW:150.17
EINECS:262-349-7
Product Categories:Aromatics Compounds;Aromatics;Aldehydes;C9;Carbonyl Compounds
Mol File:60656-87-3.mol
BENZYLOXYACETALDEHYDE Structure
BENZYLOXYACETALDEHYDE Chemical Properties
Boiling point 118-120 °C/13 mmHg (lit.)
density 1.069 g/mL at 25 °C (lit.)
refractive index n20/D 1.518(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Chloroform, Ethyl Acetate
form Oil
color Clear Colourless
Specific Gravity1.069
Stability:Temperature, Moisture Sensitive
InChIKeyNFNOAHXEQXMCGT-UHFFFAOYSA-N
LogP0.729 (est)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29124990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
BENZYLOXYACETALDEHYDE Usage And Synthesis
Chemical PropertiesPale Yellow Oil
UsesAcceptor; engineering of 2-deoxyribose 5-phosphate aldolase variants for enzymic preparation of β-ketols
UsesAcceptor; engineering of 2-deoxyribose 5-phosphate aldolase variants for enzymic preparation of -ketols
UsesBenzyloxyacetaldehyde may be used in the following syntheses:
  • (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate
  • (S)-5-benzyloxy-4-hydroxypentan-2-one
  • myxothiazols
General DescriptionBenzyloxyacetaldehyde is a non-natural aldehyde. It undergoes enantioselective Mukaiyama aldol reaction with silylketene acetal nucleophiles in the presence of C2-symmetric bis(oxazolinyl)pyridine Cu(II) complex (catalyst).
BENZYLOXYACETALDEHYDE Preparation Products And Raw materials
Preparation Products12H- [1] benzothieno [2,3-a] carbazole-->BENZYL PROPARGYL ETHER-->methyl 2-(benzyloxy)acetate-->Ethyl 4-(benzyloxy)-3-oxobutanoate-->2-(Phenylmethoxy)-acetonitrile-->2-BENZYLOXY-PROPENAL-->4H-Pyran-4-one, 2,3-dihydro-2-[(phenylmethoxy)methyl]--->(2R,3R,5S)-3,5-DiMethyl-1-benzyloxy-2-hydroxy-8-(4-Methoxyphenoxy)-4-octanone
BENZYLOXYACETALDEHYDE DIMETHYL ACETAL BENZOYL LACTIC ACID Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate BENZYLOXYACETALDEHYDE DIETHYL ACETAL (2R,6S)-(+)-4-BENZOYLOXY-2-BENZOYLOXYMETHYL-6-METHOXY-2H-PYRAN-3(6H)-ONE (+)-DIMETHYL 2,3-O-BENZYLIDENE-D-TARTRATE Dibenzoyltartaric acid ETHYL 3-PHENYLGLYCIDATE BUTYL PHTHALYL BUTYL GLYCOLATE CHALCONE ALPHA,BETA-EPOXIDE ETHYL O-BENZOYLGLYCOLATE BENZOYLOXYPHLORACETOPHENONE,OMEGA-(RG) 2,3-Di-O-para-toluoyl-D-tartaric acid DESYL BENZOATE (-)-2,3-O-BENZYLIDENE-L-TARTARIC ACID DIETHYL ESTER NARINGENIN Fluorescamine Ethyl 3-methyl-3-phenylglycidate

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