4-Aminobenzophenone

4-Aminobenzophenone Basic information
Product Name:4-Aminobenzophenone
Synonyms:P-AMINOBENZOPHENONE CRYSTALLINE;4-AMINOBENZOPHENONE(P-AMINOBENZOPHENONE, PAB);4-Aminobenzophenone98%;4-Aminophenyl phenyl ketone, 4-Benzoylaniline;4-aminobenzopenone;4-AMINOBENZOPHENONE FOR SYNTHESIS;4-AMINOPHENYL PHENYL KETONE;4-AMINOBENZOPHENONE
CAS:1137-41-3
MF:C13H11NO
MW:197.23
EINECS:214-506-6
Product Categories:Pyrimidines;Aromatic Benzophenones & Derivatives (substituted)
Mol File:1137-41-3.mol
4-Aminobenzophenone Structure
4-Aminobenzophenone Chemical Properties
Melting point 121-124 °C (lit.)
Boiling point 246 °C (12.7517 mmHg)
density 1.0957 (rough estimate)
refractive index 1.6050 (estimate)
Fp 245-247°C/22mm
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Fine Crystalline Powder
pkapK1: 2.15(+1) (25°C)
color Yellow
Water Solubility Soluble in cold water, alcohol and ether.
BRN 389292
CAS DataBase Reference1137-41-3(CAS DataBase Reference)
EPA Substance Registry SystemMethanone, (4-aminophenyl)phenyl- (1137-41-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-22
Safety Statements 26-36-37/39
WGK Germany 3
RTECS DJ0175000
8-10-23
TSCA Yes
HazardClass IRRITANT
HS Code 29223990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-Aminobenzophenone Usage And Synthesis
Chemical PropertiesYELLOW FINE CRYSTALLINE POWDER
Uses4-Aminobenzophenone is associated with 4-benzoylpyridine and it is used as a frequency doubler for semiconductor lasers. It is used in the preparation of 1-[4-[N,N-bis(trimethylsilyl)amino]phenyl]-1-phenylethylene. It is used as a precursor to prepare 1,2,3-triazoles, pyrimidotriazoles, benzothiazole and pyrimidinone derivatives. It is involved in the formation of coordination complexes with chromium(III).
Synthesis Reference(s)Tetrahedron Letters, 39, p. 1313, 1998 DOI: 10.1016/S0040-4039(97)10877-2
General Description4-Aminobenzophenone (4-ABP) is the best derivative of benzophenone with 260 times higher second harmonic generation (SHG) efficiency than potassium dihydrogen phosphate (KDP), growth of high quality bulk crystal still remains a difficult task.
Safety ProfilePoison by intraperitoneal route. See also KETONES and AMINES. When heated to decomposition it emits toxic fumes of NOx,.
Purification MethodsDissolve it in aqueous acetic acid, filter and precipitate it with ammonia. This process is repeated several times, then the amine is recrystallised from aqueous EtOH. [Beilstein 14 IV 248.]
4-Aminobenzophenone Preparation Products And Raw materials
Preparation Products4-ISOCYANOBENZOPHENONE-->1-(4-BroMophenyl)-1,2,2-triphenylethylene-->1-(4-benzoylphenyl)-3-phenylthiourea
1,2-DIHYDROXY-3-NITROANTHRAQUINONE FMOC-2-AMINOBENZOPHENONE-2'-CARBOXYLIC ACID 4,4'-Diaminobenzophenone 2,6-Diaminoanthraquinone 3,4-DIAMINOBENZOPHENONE MONOHYDROCHLORIDE (Z)-2-Aminobenzophenone oxime (3,4-Diaminophenyl)phenylmethanone (E)-2-Aminobenzophenone oxime (S)-(-)-2-(N-BENZYLPROPYL)AMINOBENZOPHENONE,(S)-(-)-2-(N-BENZYLPROLYL)AMINOBENZOPHENONE 3-nitrofluoren-9-one 4-MORPHOLINOBENZOPHENONE 5-Nitro-2-aminobenzophenone-d5 5-CHLORO-2''-FLUORO-2(HYDROXYETHYL)AMINOBENZOPHENONE 2,2'-Diaminobenzophenone 2-AMINO-1-BROMO-3-CHLOROANTHRAQUINONE 2-acetamido-3-nitro-9-fluorenone 3,3',4,4'-TETRA AMINOBENZOPHENONE 3.3'.4.4'-TETRA AMINOBENZOPHENONE

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