ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Methyl ester compound METHYL ALPHA-BROMOPHENYLACETATE

METHYL ALPHA-BROMOPHENYLACETATE

METHYL ALPHA-BROMOPHENYLACETATE Basic information
Product Name:METHYL ALPHA-BROMOPHENYLACETATE
Synonyms:Methyl alpha-bromobenzeneacetate;Methyl bromophenylacetate;Methyl2-bromo-2-phenylacetate;Methyla-bromo-a-phenylacetate;Methyla-bromobenzeneacetate;ALPHA-BROMOPHENYLACETIC ACID METHYL ESTER;METHYL (+/-)-ALPHA-BROMOPHENYLACETATE;METHYL ALPHA-BROMOPHENYLACETATE
CAS:3042-81-7
MF:C9H9BrO2
MW:229.07
EINECS:608-480-9
Product Categories:Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Aromatic Phenylacetic Acids and Derivatives;C8 to C9;Carbonyl Compounds;Esters
Mol File:3042-81-7.mol
METHYL ALPHA-BROMOPHENYLACETATE Structure
METHYL ALPHA-BROMOPHENYLACETATE Chemical Properties
Boiling point 113 °C3 mm Hg(lit.)
density 1.46 g/mL at 20 °C(lit.)
refractive index n20/D 1.554
Fp >230 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
BRN 1102743
InChIKeyNHFBYYMNJUMVOT-UHFFFAOYSA-N
Safety Information
Hazard Codes C
Risk Statements 36/37/38-34
Safety Statements 26-36/39-45-36/37/39
RIDADR UN 3265 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup II
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
METHYL ALPHA-BROMOPHENYLACETATE Usage And Synthesis
Chemical PropertiesLight yellow to yellow liquid
UsesMethyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
Synthesis Reference(s)Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6
General DescriptionMethyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
METHYL ALPHA-BROMOPHENYLACETATE Preparation Products And Raw materials
ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER BROMO-(4-FLUORO-PHENYL)-ACETIC ACID ETHYL ESTER A-BROMO-2,4-DICHLOROBENZENEACETIC ACID ETHYL ESTER (3-BROMOPHENYL)ACETIC ACID METHYL ESTER ETHYL 2-BROMO-2-PHENYLPROPANOATE Methyl α-bromo-p-chlorophenylacetate BROMO-P-TOLYL-ACETIC ACID METHYL ESTER DIMETHYL 2-BROMO-2-(4-NITROPHENYL)MALONATE METHYL 2-BROMO-2-(2-CYANOPHENYL)ACETATE ISOAMYL ALPHA-BROMOPHENYLACETATE METHYL (+/-)-ALPHA-BROMOPHENYLACETATE,METHYL ALPHA-BROMOPHENYLACETATE 2'-BROMO-3,4-DICHLOROPHENYLACETIC ACID METHYL ESTER ETHYL 2-BROMO-(4-BROMOPHENYL)ACETATE METHYL ALPHA-BROMO-2-CHLOROPHENYLACETATE Methyl α-bromo-o-chlorophenylacetate METHYL 2-BROMO-2-(4'-CYANOPHENYL)ACETATE Methyl 4-bromophenylacetate METHYL 2-BROMO-2-(2-NITROPHENYL) ACETATE
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