ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Acyclic hydrocarbons (1E)-1-Iodo-1-hexene

(1E)-1-Iodo-1-hexene

(1E)-1-Iodo-1-hexene Basic information
Product Name:(1E)-1-Iodo-1-hexene
Synonyms:(1E)-1-Iodo-1-hexene;(E)-1-Hexenyl iodide;(E)-1-Iodo-1-hexene;trans-1-Iodo-1-hexene;1(E)-Iodo-hex-1-ene;1-Hexene, 1-iodo-, (1E)-;1-iodohex-1-ene;(1E)-1-Iodo-1-hexene ISO 9001：2015 REACH
CAS:16644-98-7
MF:C6H11I
MW:210.06
EINECS:
Product Categories:Acyclic;Alkenes;Building Blocks;Chemical Synthesis;Organic Building Blocks
Mol File:16644-98-7.mol
(1E)-1-Iodo-1-hexene Structure
(1E)-1-Iodo-1-hexene Chemical Properties
Boiling point 151.64°C (estimate)
density 1.4517 (rough estimate)
refractive index n20/D 1.509
BRN 1840329
Safety Information
Hazard Codes Xn,N
Risk Statements 22-51/53
Safety Statements 61
RIDADR UN 3082 9 / PGIII
WGK Germany 3
MSDS Information
(1E)-1-Iodo-1-hexene Usage And Synthesis
UsesPalladium-catalyzed carboalkoxylation gives appreciable stereospecific vinylic halides, including trans-1-Iodohexene. Also, trans-1-Iodohexene cross coupled with (E)??- or (Z)??-??vinylstannanes gives good yields of stereoisomerically pure unsymmetrical dienes with the same double bond geometry
Synthesis Reference(s)Tetrahedron Letters, 15, p. 543, 1974 DOI: 10.1016/S0040-4039(01)82266-8
The Journal of Organic Chemistry, 54, p. 6064, 1989 DOI: 10.1021/jo00287a017
(1E)-1-Iodo-1-hexene Preparation Products And Raw materials
Preparation ProductsN-BOC PRROLIDIN-2-OL-->1-[(E)-1-Hexenyl]cyclohexan-1-ol
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