4-AZIDOANILINE HYDROCHLORIDE

4-AZIDOANILINE HYDROCHLORIDE Basic information
Product Name:4-AZIDOANILINE HYDROCHLORIDE
Synonyms:4-AMINOPHENYL AZIDE HYDROCHLORIDE;4-AZIDOANILINE HYDROCHLORIDE;4-Azidoaniline hydrochloride 97%;4-Azidoaniline HCl
CAS:91159-79-4
MF:C6H7ClN4
MW:170.6
EINECS:628-425-2
Product Categories:
Mol File:91159-79-4.mol
4-AZIDOANILINE HYDROCHLORIDE Structure
4-AZIDOANILINE HYDROCHLORIDE Chemical Properties
Melting point 165 °C (dec.)(lit.)
solubility methanol: soluble
BRN 7942921
Safety Information
Hazard Codes F,T
Risk Statements 11-23/24/25-36/37/38
Safety Statements 16-26-33-36/37-45
RIDADR UN 2926 4.1/PG 2
WGK Germany 3
3-8-10
HazardClass 4.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
4-AZIDOANILINE HYDROCHLORIDE Usage And Synthesis
Uses4-Azidoaniline hydrochloride is suitable for use in the preparation of photo-reactive polymers, poly(acrylic acid) having encorporated phenylazido groups. It may be used in the preparation of 1-(4-aminophenyl)-1H-[1,2,3]-triazol-4-ylcarbonyl-Phe-Gly-Phe-Gly-OH. It is suitable for use in the synthesis of photo-reactive polysaccharides.
Purification MethodsPurify it in EtOAc with dry HCl gas followed by cold dry Et2O. The free base has m 66o(dec) (MeOH) and the picrate has m 64-65o(dec) (MeOH). The IR has max (Nujol) at 2110cm-1 (N3). [Escher et al. Helv Chim Acta 62 1217 1979, Maffei & Rivolta Gazetta Chim Ital 84 750 1954, Beilstein 12 H 772, 12 IV 1741.]
4-AZIDOANILINE HYDROCHLORIDE Preparation Products And Raw materials
AZIDOIMIPRAMINE 4-AZIDOANILINE HYDROCHLORIDE PHENYL AZIDE

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