4-Bromo-N,N-dimethylaniline

4-Bromo-N,N-dimethylaniline Basic information
Product Name:4-Bromo-N,N-dimethylaniline
Synonyms:P-BROMO-N,N-DIMETHYLANILINE;N,N-DIMETHYL-P-BROMOANILINE;p-N,N-Dimethylaminobromobenzene;N-(4-BROMOPHENYL)-N,N-DIMETHYLAMINE;(4-Bromo-phenyl)-dimethyl-amine;1-Bromo-4-(dimethylamino)benzene;4-(Dimethylamino)phenyl bromide;4-(dimethylamino)phenylbromide
CAS:586-77-6
MF:C8H10BrN
MW:200.08
EINECS:209-582-2
Product Categories:Miscellaneous;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Anilines, Aromatic Amines and Nitro Compounds;Amines;C8;Nitrogen Compounds;Aniline;bc0001;586-77-6
Mol File:586-77-6.mol
4-Bromo-N,N-dimethylaniline Structure
4-Bromo-N,N-dimethylaniline Chemical Properties
Melting point 52-54 °C (lit.)
Boiling point 264 °C (lit.)
density 1.3220
refractive index 1.5748 (estimate)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform, Methanol
pka4.23(at 25℃)
form Crystalline Solid
color White to gray or light blue
Water Solubility Soluble in methanol. Insoluble in water.
BRN 2206155
Stability:Stable. Incompatible with oxidizing agents, acids, metals.
InChIKeyXYZWMVYYUIMRIZ-UHFFFAOYSA-N
CAS DataBase Reference586-77-6(CAS DataBase Reference)
NIST Chemistry Reference4-Bromo-N,N-dimethylaniline(586-77-6)
EPA Substance Registry SystemN,N-Dimethyl-p-bromoaniline (586-77-6)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 20/21/22-36/38-33-22
Safety Statements 26-36-45-37-28A
RIDADR 2811
WGK Germany 3
RTECS BW9300000
8
Hazard Note Irritant
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29214290
MSDS Information
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4-Bromo-N,N-dimethylaniline English
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4-Bromo-N,N-dimethylaniline Usage And Synthesis
Chemical Propertieswhite to light grey powder
Uses4-Bromo-N,N-dimethylaniline is used as an internal standard in the determination of iodine present as iodide (as in pharmaceuticals), iodate (as in iodized table salt) and covalently bound to organic compounds (as in milk and vegetables).
Purification MethodsReflux the aniline for 3hours with two equivalents of acetic anhydride, then fractionally distil it under reduced pressure. [Beilstein 12 IV 1499.]
DIBROMOBAPTA 4-BROMO-2,6-DIMETHYLANILINE HYDROCHLORIDE 4-BROMO-3,5-DIMETHYLANILINE 6-bromo-3-methyl-3H-dibenz[f,ij]isoquinoline-2,7-dione N-(4-BROMOPHENYL)SUCCINIMIDE N-(4-BROMOPHENYL)PHTHALIMIDE 4-BROMO-2,5-DIMETHYLANILINE,4-Bromo-2,5-dimethylaniline 96% 2-bromo-N,4-dimethylaniline 4,4'-DIBROMOTRIPHENYLAMINE CHEMBRDG-BB 5304453 5-BROMO-2,4-DIMETHYLANILINE 4-BROMO-N,N-DIETHYLANILINE 1-(4-BROMOPHENYL)-2-THIOXO-1,2,3,4-TETRAHYDROPYRIDO[2,3-D]PYRIMIDIN-4-ONE 2,4-DIBROMO-3,6-DIMETHYLANILINE 1-(4-BROMOPHENYL)IMIDAZOLINE-2-THIONE 1-(4-bromo-2-nitrophenyl)piperidine N1-[5-BROMO-4-(CHLOROMETHYL)-1,3-THIAZOL-2-YL]-N1-(4-BROMOPHENYL)ACETAMIDE 4-Bromo-2,3-dimethylaniline 98%,4-BROMO-2,3-DIMETHYLANILINE

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