1,2,4-Trimethoxybenzene

1,2,4-Trimethoxybenzene Basic information

Product Name:	1,2,4-Trimethoxybenzene
Synonyms:	HYDROXYHYDROQUINONE TRIMETHYL ETHER;1,2,4-TRIMETHOXYBENZENE;1,2,4-trimethoxy-benzen;Benzene, 1,2,4-trimethoxy-;1.2.4-Trimethoxy benzone;1,2,4-Benzenetriol trimethyl ether;TMB 124;1,4,5-Trimethoxybenzene
CAS:	135-77-3
MF:	C9H12O3
MW:	168.19
EINECS:	205-219-7
Product Categories:	Building Blocks;C9;Chemical Synthesis;Ethers;Organic Building Blocks;Oxygen Compounds;Aromatic Hydrocarbons (substituted) & Derivatives;Benzene derivates;Anisoles, Alkyloxy Compounds & Phenylacetates;bc0001
Mol File:	135-77-3.mol

1,2,4-Trimethoxybenzene Chemical Properties

Boiling point	247 °C(lit.)
density	1.126 g/mL at 25 °C(lit.)
refractive index	n20/D 1.533(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform, Ethyl Acetate
form	Oil
color	Clear Colourless
Water Solubility	Not miscible in water.
Merck	14,1073
BRN	2047579
LogP	1.640 (est)
CAS DataBase Reference	135-77-3(CAS DataBase Reference)
NIST Chemistry Reference	1,2,4-Trimethoxybenzene(135-77-3)
EPA Substance Registry System	1,2,4-Trimethoxybenzene (135-77-3)

Safety Information

Hazard Codes	Xi
Safety Statements	23-24/25
WGK Germany	3
RTECS	DC2770000
Hazard Note	Irritant
TSCA	Yes
HS Code	29093090

MSDS Information

Provider	Language
1,2,4-Trimethoxybenzene	English
SigmaAldrich	English
ACROS	English
ALFA	English

1,2,4-Trimethoxybenzene Usage And Synthesis

Chemical Properties	clear light yellow to yellow-brown liquid
Uses	1,2,4-Trimethoxybenzene is used as a reagent in the synthesis of barbigerone derivatives which can be used as antiproliferative and antiangiogenesis agents. Also used as a reagent in the synthesis of Malvone A (M161525) which is a phytoalexin found in Malva sylvestris.
Definition	ChEBI: 1,2,4-Trimethoxybenzene is a member of methoxybenzenes.

1,2,4-Trimethoxybenzene Preparation Products And Raw materials

Raw materials	Hydrogen peroxide-->Dimethyl sulfate-->Sodium dichromate dihydrate-->Hydroquinone-->Vanillin-->1,2,4-Triacetoxybenzene
Preparation Products	2,4,5-Trimethoxynitrobenzene -->BENZENE,1,2,4-TRIMETHOXY-5-(2-PROPENYL)--->METHOXYBENZOQUINONE-->CHEMBRDG-BB 5175563

PRECOCENE II trans-2,4,5-Trimethoxycinnamic acid 4-Methoxybenzyl cyanide 7-ETHOXY-6-METHOXY-2,2-DIMETHYLCHROMENE 6,7-DIACETOXY-4-METHYLCOUMARIN SCOPARONE β-Asarone, cis-1-Propenyl-2,4,5-trimethoxybenzene 1-CHLOROMETHYL-2,3,4-TRIMETHOXYBENZENE 1-Bromo-2,4,6-trimethoxybenzene 98% 2-(1-amino-2-ethylhexyl)-1,3,5-trimethoxybenzene 3,4,5-Trimethoxybenzyl alcohol 6,7-DIMETHOXY-4-METHYLCOUMARIN 2,4,5-TRIMETHOXYBENZYL ALCOHOL 2,3,4-TRIMETHOXYBENZYL ALCOHOL 6,7-DIMETHOXY-2,2-DIMETHYL-4-CHLOROMANONE 5-(1, 5-Diazabicyclo[3.2.1]oct-8-yl)-1,2,3-trimethoxybenzene 2,4,6-TRIMETHOXYBENZYL ALCOHOL 1,2,3,4-TETRAMETHOXY-10-METHYLACRIDONE

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