AMYL FORMATE

AMYL FORMATE Basic information
Product Name:AMYL FORMATE
Synonyms:FEMA 2068;FORMIC ACID AMYL ESTER;FORMIC ACID N-AMYL ESTER;FORMIO ACID PENTYL ESTER;N-AMYL FORMATE;PENTYL FORMATE;N-PENTYL FORMATE;AMYL FORMATE
CAS:638-49-3
MF:C6H12O2
MW:116.16
EINECS:211-340-6
Product Categories:A-B;Alphabetical Listings;Flavors and Fragrances
Mol File:638-49-3.mol
AMYL FORMATE Structure
AMYL FORMATE Chemical Properties
Melting point -73.5℃
Boiling point 132 °C (lit.)
density 0.884 g/mL at 25 °C (lit.)
vapor pressure 70 hPa (50 °C)
FEMA 2068 | AMYL FORMATE
refractive index n20/D 1.399(lit.)
Fp 83 °F
storage temp. Store below +30°C.
form clear liquid
color Colorless to Almost colorless
Odorat 10.00 % in dipropylene glycol. powerful ethereal fruity unrip banana green earthy
Odor Typefruity
explosive limit1.7-10%(V)
Water Solubility 2.904g/L(22 ºC)
JECFA Number119
LogP2.786 at 25℃
CAS DataBase Reference638-49-3(CAS DataBase Reference)
EPA Substance Registry SystemFormic acid, pentyl ester (638-49-3)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37
Safety Statements 24
RIDADR UN 1109 3/PG 3
WGK Germany 2
RTECS LQ9370000
HS Code 2915 13 00
HazardClass 3.2
PackingGroup III
ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
AMYL FORMATE Usage And Synthesis
Chemical PropertiesAmyl formate has a fruit-like aroma
Chemical PropertiesColorless liquid composed of a mixture of isomeric amyl formates with isoamyl formate in predominance. Plum-like odor. Less odoriferous and more active solvent than amyl acetate. It also has both a lower boiling point and a higher rate of evaporation. Miscible with oils, hydrocarbons, alcohols, ketones; slightly soluble in water.
OccurrenceIdentified in apple, strawberry, tomato, fried cured pork, cognac, honey and Pyrus malus
UsesSolvent for cellulose esters, resins; solvent mixtures; films and coatings; perfume for leather; flavoring.
PreparationFrom n-amyl alcohol and formic acid in the presence of H2SO4
DefinitionChEBI: Pentyl formate is a carboxylic ester.
General DescriptionA clear colorless liquid with a plum-like odor. Flash point 79°F. Less dense than water and insoluble in water. Vapors are heavier than air.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileAMYL FORMATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
HazardFlammable, dangerous fire risk. Toxic by ingestion and inhalation.
Health HazardMay cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and ExplosibilityFlammable
Safety ProfileVery low toxicity by several routes. A skin irritant. See also ESTERS. Dangerously flammable; reacts vigorously with heat, flame, oxidizing materials. To fight fire, use foam, Co2, dry chemical.
AMYL FORMATE Preparation Products And Raw materials
Raw materialsCARBON MONOXIDE-->1-Pentanol
Preparation ProductsPentyl cinnamate-->4-HYDROXYBENZOIC ACID N-AMYL ESTER-->FEMA 2079-->3H-Imidazo[4,5-c]pyridine,3-ethyl-(9CI)
CHLOROFORMIC ACID N-OCTYL ESTER Cholesteryl oleyl carbonate ISOPULEGYL ACETATE (-)-DIHYDROCARVYL ACETATE Dodecyl gallate (-)-CARVYL PROPIONATE Pregnenolone acetate L-CARVYL ACETATE L-MENTHYL ACETATE CHOLESTERYL CHLOROACETATE 2-furoic acid amyl ester N-AMYL FORMATE, (FORMIC ACID N-AMYL ESTER) Octyl gallate FEMA 2348 Cortisone acetate Cholesteryl chloroformate ISO-AMYL-FORMATE FCC 3-PENTYL FORMATE,3-AMYL FORMATE

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