2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL

2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL Basic information
Reaction
Product Name:2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
Synonyms:2'-[Bis(1,1-dimethylethyl)phosphino]-N,N-dimethyl-[1,1'-biphenyl]-2-amine;2-Di-tert-butylphosphino-2'-(N,N-dimethylamino)biphenyl,98%;2-[2-(di-tert-butylphosphanyl)phenyl]-N,N-diMethylaniline;98% tBuDavePhos;2'-(Di-tert-butylphosphino)-N,N-diMethyl-[1,1'-biphenyl]-2-aMine;2-(Di-tert-butylphosphiNA)-2'-(N,N-diMethylaMiNA)biphenyl;2-(Di-tert-butylphosphino)-2'-;2-Di-t-butylphosphino-2'-(N,N-diMethylaMino)biphenyl,98% tBuDavePhos
CAS:224311-49-3
MF:C22H32NP
MW:341.47
EINECS:607-073-3
Product Categories:Phosphines;Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:224311-49-3.mol
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL Structure
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL Chemical Properties
Melting point 115-117 °C
Boiling point 451.6±38.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
pka5.07±0.18(Predicted)
form crystal
color white
Sensitive Air Sensitive
InChIKeyPHLPNEHPCYZBNZ-UHFFFAOYSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26
WGK Germany 3
TSCA No
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL Usage And Synthesis
Reaction
  1. Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions.
  2. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines.
  3. Ligand used for selective Pd-catalyzed silylation of aryl chlorides.
  4. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. 
Reactions of 224311-49-3
Chemical PropertiesWhite crystals or crystalline powder
Usessuzuki reaction
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL Preparation Products And Raw materials
Preparation ProductsMethanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-biphenyl, Min. 98% Cphos 2-DIPHENYLPHOSPHINO-6-METHYLPYRIDINE 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISO& 2'-(Dicyclohexylphosphino)-N,N-dimethyl[1,1'-biphenyl]-4-amine 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl 2-(Dicyclohexylphosphino)-2'-methylbiphenyl 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL 2-(Di-tert-butylphosphino)biphenyl Di-tert-butylphosphine T-BUTYLPHOSPHINE 2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL DI-TERT-BUTYLPHENYLPHOSPHINE

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