ChemicalBook Product Catalog Chemical Reagents Silane reagent TERT-BUTYLDIMETHYLSILANOL

TERT-BUTYLDIMETHYLSILANOL

TERT-BUTYLDIMETHYLSILANOL Basic information
Product Name:TERT-BUTYLDIMETHYLSILANOL
Synonyms:TERT-BUTYLDIMETHYLSILANOL;Butyldimethylsilanol;Silanol, (1,1-dimethylethyl)dimethyl-;SIB1939.0 !! T-BUTYLDIMETHYLSILANOL;tert-ButyldiMethylsilanol 99%;tert-Butyl-hydroxy-Dimethylsilane;tert-Butyldimethyl(hydroxy)silane;tert-Butyldimethylhydroxysilane
CAS:18173-64-3
MF:C6H16OSi
MW:132.28
EINECS:
Product Categories:Organometallic Reagents;Organosilicon;Silanols
Mol File:18173-64-3.mol
TERT-BUTYLDIMETHYLSILANOL Structure
TERT-BUTYLDIMETHYLSILANOL Chemical Properties
Melting point 18 °C
Boiling point 139 °C/739 mmHg (lit.)
density 0.84 g/mL at 25 °C (lit.)
refractive index n20/D 1.424(lit.)
Fp 113 °F
solubility soluble in Benzene
form clear liquid
pka15.37±0.53(Predicted)
Specific Gravity0.840
color Colorless to Almost colorless
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 1732777
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36
RIDADR UN 1987 3/PG 3
WGK Germany 3
F 10-21
TSCA No
HS Code 2931.90.9010
HazardClass 3.2
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
TERT-BUTYLDIMETHYLSILANOL Usage And Synthesis
Usestert-Butyldimethylsilanol can be used as a silylating agent for the protection of hydroxyl groups via silylation. It is used:
  • For the preparation of α-chiral ether derivatives by catalytic asymmetric allylic substitution.
  • As an initiator for the polymerization of 1,2 benzenedicarboxaldehyde.
  • In the synthesis of enol silyl ethers.

TERT-BUTYLDIMETHYLSILANOL Preparation Products And Raw materials
Raw materials(TERT.-BUTYLDIMETHYLSILYLOXY)ETHANOL-->Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester
T-BUTYLDIPHENYLMETHOXYSILANE 3-(tert-Butyldimethylsilyloxy)glutaric anhydride (3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one TRIS(TERT-BUTYLDIMETHYLSILYL) PHOSPHITE P-(T-BUTYLDIMETHYLSILOXY)STYRENE N2-(ISOBUTYRYL)-5'-O-(DIMETHOXYTRITYL)-2'-O-(T-BUTYLDIMETHYLSILYL)-GUANOSINE-3'-N,N-DIISOPROPYL (CYANOETHYL) PHOSPHORAMIDITE N-Benzoyl-5'-O-(4,4-Dimethoxytrityl)-2'-O-[(tert-butyl)dimethylsilyl]adenosine-3'-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite TERT-BUTYLDIMETHYLSILANOL 2-(TERT-BUTYLDIMETHYLSILOXY)PENT-2-EN-4-ONE Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester N-blocked-5'-O-DMT-2'-O-TBDMS CED cytidine phosphoramidite DIMETHYLSILANE 5-(TERT-BUTYLDIMETHYLSILYLOXY)-1-PENTANOL 3-(T-BUTYLDIMETHYLSILOXY)PROPANOL DIMETHYL-(2,3-DIMETHYL-2-BUTYL)SILYL TRIFLUOROMETHANESULFONATE 5'-O-(4,4-Dimethoxytrityl)-2'-O-[(tert-butyl)dimethylsilyl]uridine-3'-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite O-(TERT-BUTYLDIMETHYLSILYL)HYDROXYLAMINE TRI-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL
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