DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE

DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE Basic information
Product Name:DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE
Synonyms:Carbamic acid, diethyldithio-, compd. with diethylamine (1:1);Carbamic acid, diethyldithio-, diethylamine salt;Carbamodithioic acid, diethyl-, compd. with N-ethylethanamine (1:1);Carbamodithioicacid,diethyl-,compd.withN-ethylethanamine(1:1);Contramine;Diaethylammonium-diaethyldithiocarbamat;DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE;DIETHYLDITHIOCARBAMIC ACID DIETHYLAMMONIUM SALT
CAS:1518-58-7
MF:C9H22N2S2
MW:222.41
EINECS:216-175-3
Product Categories:Aliphatics;Amines;Sulfur & Selenium Compounds
Mol File:1518-58-7.mol
DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE Structure
DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE Chemical Properties
Melting point 82-84 °C(lit.)
Boiling point 125 °C
density 1.0490 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. Refrigerator
solubility Soluble in Chloroform, Methanol.
form Solid
color White to Off-White
Water Solubility almost transparency
Sensitive Hygroscopic
InChIKeyNBGTWXBPCIHUQD-UHFFFAOYSA-N
CAS DataBase Reference1518-58-7(CAS DataBase Reference)
EPA Substance Registry SystemDiethylammonium diethyldithiocarbamate (1518-58-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS EZ5425000
TSCA Yes
HS Code 2930.20.9050
Toxicitymouse,LD50,intraperitoneal,500mg/kg (500mg/kg),National Technical Information Service. Vol. AD277-689,
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE Usage And Synthesis
Chemical PropertiesWHITE TO OFF-WHITE CRYSTALLINE POWDER
UsesIn water-chloroform mixtures the reagent is found quantitatively in the aqueous phase at pH > 8, while it remains quantitatively in the organic phase at pH < 4.
The reagent reacts with essentially the same metal ions as does the sodium salt of diethyldithiocarbamate. However, it possesses the advantageous feature that some metal ions can be extracted with it from more acidic solutions, which in some cases may result in an increase of analytical selectivity.
The analytical applicability of several substituted dithiocarbamates has also been examined. Hulanicki demonstrated the effects of various substituents in the reagent upon the properties of the corresponding complexes. In the main the majority of analytical problems can be solved equally well with diethyldithiocarbamate itself. Substitution of the reagent enhances the efficiency of the ligand in some special cases only.

UsesDiethylammonium diethyldithiocarbamate is used in the synthesis of Dithiocarbamate. It serve as hosts for the specific binding of various metal cations.
DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE Preparation Products And Raw materials
Raw materialsDiethylamine-->Carbon disulfide
Piperidine pentamethylenedithiocarbamate CYCLOHEXYLETHYLDITHIOCARBAMIC ACID N-CYCLOHEXYLETHYLAMMONIUM SALT Disulfiram Zinc dibenzyldithiocarbamate Bis(pentamethylene)thiuram tetrasulfide TETRAISOPROPYLTHIURAM DISULFIDE CADMIUM CYCLOPENTAMETHYLENE DITHIOCARBAMATE DIPENTAMETHYLENETHIURAM MONOSULFIDE PENTEX DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE ZINC DIETHYLDITHIOCARBAMATE HEXAMETHYLENEAMMONIUM HEXAMETHYLENEDITHIOCARBAMATE BIS (4-METHYL-1-HOMO-PIPERAZINYLTHIOCARBONYL) DISULFIDE DICYCLOPENTAMETHYLENETHIURAM DISULFIDE DIBENZYLAMMONIUM DIBENZYLDITHIOCARBAMATE TETRA-N-BUTYLTHIURAM DISULFIDE 4-MORPHOLINECARBODITHIOIC ACID COMPOUND WITH MORPHOLINE 1:1 BIS(2-HYDROXYETHYL)DITHIOCARBAMIC ACID COPPER SALT

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