Prussian Blue

Prussian Blue Basic information
Product Name:Prussian Blue
Synonyms:Pigment Blue 27;ferrihexacyanoferrate;ferrocin;ferrotsin;hexacyano-ferrate(4-iron(3+)(3:4);hexakis(cyano-C)-iron(3+)(3:4),(OC-6-11)-Ferrate(4-);iron(3+)(3:4),(oc-6-11)-ferrate(4-hexakis(cyano-c)-;iron(3+)ferrocyanide
CAS:14038-43-8
MF:C6FeN6.4/3Fe
MW:859.23
EINECS:237-875-5
Product Categories:Dyes and Pigments;Inorganics
Mol File:14038-43-8.mol
Prussian Blue Structure
Prussian Blue Chemical Properties
density 1.8
storage temp. Room Temperature
form Powder
color Dark blue
Water Solubility practically insoluble
Sensitive Hygroscopic
Merck 14,7910
Solubility Product Constant (Ksp)pKsp: 40.52
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 1 mg/m3
Stability:Stable. Incompatible with strong acids, strong oxidizing agents, ammonia. Light sensitive.
LogP-0.250 (est)
EPA Substance Registry SystemIron ferrocyanide (Fe4[Fe(CN)6]3) (14038-43-8)
Safety Information
Safety Statements 22-24/25
WGK Germany 1
RTECS LJ8200000
TSCA Yes
HS Code 32041990
Hazardous Substances Data14038-43-8(Hazardous Substances Data)
Toxicitymouse,LD,oral,> 8gm/kg (8000mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
MSDS Information
ProviderLanguage
C.I. 77510 English
SigmaAldrich English
ACROS English
ALFA English
Prussian Blue Usage And Synthesis
DescriptionIron blue is chemically referred to as ferric ammonium ferrocyanide Fe(Fe(CN)6)3. This material is generated through the reaction of sodium ferrocyanide and ferrous sulfate in the presence of ammonium sulfate. Pigments prepared with sodium or potassium salts are called ferric ferrocyanide.
Chemical Propertiesdark blue crystalline powder
UsesPrussian blue (KFe(Fe(CN)6)) is an intense reddish blue pigment with fairly good properties. It is used as a coloring pigment in many types of paint systems and is also used in the production of lead chrome greens.
UsesIron(III) hexacyanoferrate(II) is uses extensively as an Iron Oxide dye. Prussian blue is used as a paint and wallpaper printing, chemical coatings, carbon paper and in the plastics industry. as an antidote for poisoning with radioactive cesium or thallium. In the metalworking and mechanical engineering Prussian blue is thinly applied as a paste on metal surfaces in order to assess the quality scraped surfaces can.
DefinitionThe most common and best- known name for blue iron ferrocyanide (iron blue) pigments made by a variety of procedures.
Flammability and ExplosibilityNotclassified
iron Prussian Blue Pigment Red 149 FERROCYANIDE pig iron Ferric chloride Pearl pigment 15 PIGMENT BLUE 15 Cyanide, Quant Test Strips Copper(II) phthalocyanine Sodium cyanide Sodium ferrocyanide PIGMENT BLACK Potassium ferrocyanide trihyrate Direct Blue 14 SODIUM NITROPRUSSIDE Pigment Geen 7 Ammonium ferric citrate

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