ChemicalBook Product Catalog Organic Chemistry Phosphines 1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane Basic information
Product Name:1,3-Bis(diphenylphosphino)propane
Synonyms:1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;1,3-BIS(DIPHENYLPHOSPHINO)PROPANE;DPPP;TRIMETHYLENEBIS(DIPHENYLPHOSPHINE);[3-(Diphenylphosphino)propyl](diphenyl)phosphine;1,3-Propanediylbis(diphenylphosphine);Bis(1,3-diphenylphosphino)propane;Phosphine, 1,3-propanediylbis[diphenyl-
CAS:6737-42-4
MF:C27H26P2
MW:412.45
EINECS:229-791-2
Product Categories:Phosphine Ligands;Synthetic Organic Chemistry;Ligand;API intermediates;organophosphine ligand;API intermediate;Phosphines;Achiral Phosphine;Aryl Phosphine
Mol File:6737-42-4.mol
1,3-Bis(diphenylphosphino)propane Structure
1,3-Bis(diphenylphosphino)propane Chemical Properties
Melting point 63-65 °C (lit.)
Boiling point 529.7±33.0 °C(Predicted)
Fp 235°C
storage temp. Inert atmosphere,Room Temperature
form Granules or Powder
color White to light yellow-beige
Water Solubility insoluble
Sensitive Air Sensitive
BRN 2821785
InChIInChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKeyLVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILESP(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry SystemPhosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-36
WGK Germany 3
F 10-23
TSCA Yes
HS Code 29310095
MSDS Information
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1,3-Bis(diphenylphosphino)propane English
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1,3-Bis(diphenylphosphino)propane Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.
(S)-1-[(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL]-ETHYLDI(3,5-XYLYL)PHOSPHINE Di(trimethylol propane) (R)-1-[(S)-2-[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE 1,3-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]PROPANE [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Diphenylmethane DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) 1,3-Bis(diphenylphosphino)propane CIS,CIS,CIS-TETRAKIS(DIPHENYLPHOSPHINOMETHYL)CYCLOPENTANE (R)-1-[(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE (2R,4R)-(+)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE (S)-1-[(R)-2-[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE (S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI(3,5-XYLYL)PHOSPHINE (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE(NORBORNADIENE)RHODIUM(I)HEXAFLUOROPHOSPHATE 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE MONOOXIDE,1,3-BIS(DIPHENYLPHOSPHINO)PROPANE MONOXIDE,1,3-Bis(diphenylphosphino)propane monooxide, min. 97% tert-Butylchlorodiphenylsilane BIS-Tris Propane
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