1,4-Butanediol diglycidyl ether

1,4-Butanediol diglycidyl ether Basic information
Product Name:1,4-Butanediol diglycidyl ether
Synonyms:1,4-Butanediol diglycidyl ether >=95%;1,4-Butanediol diglycidyl ether technical grade, 60%;1,4-Butanediol diglycidyl ether, 98%, 98%;1,4-butandedioldiglycidylether;1,4-Butane diglycidyl ether;1,4-butanediglycidylether;2-([4-(2-Oxiranylmethoxy)butoxy]methyl)oxirane;2,2'-[1,4-Butanediylbis(oxymethylene)]bis[oxirane]
CAS:2425-79-8
MF:C10H18O4
MW:202.25
EINECS:219-371-7
Product Categories:Epoxy Diluents;Epoxide Monomers;Monomers;Polymer Science;Oxiranes;Simple 3-Membered Ring Compounds;bc0001;2425-79-8
Mol File:2425-79-8.mol
1,4-Butanediol diglycidyl ether Structure
1,4-Butanediol diglycidyl ether Chemical Properties
Melting point -21 °C
Boiling point 266 °C (lit.)
density 1.1 g/mL at 25 °C (lit.)
vapor pressure ~10 mm Hg ( 20 °C)
refractive index n20/D 1.453
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Soluble), Methanol (Slightly)
form Liquid
Specific Gravity1.07
color Clear yellow
Water Solubility SOLUBLE
Sensitive Hygroscopic
BRN 115238
Stability:Hygroscopic
InChIKeySHKUUQIDMUMQQK-UHFFFAOYSA-N
LogP-0.27 at 25℃
CAS DataBase Reference2425-79-8(CAS DataBase Reference)
NIST Chemistry ReferenceOxirane, 2,2'-[1,4-butanediylbis(oxymethylene)]bis-(2425-79-8)
EPA Substance Registry System1,4-Butanediol diglycidyl ether (2425-79-8)
Safety Information
Hazard Codes Xn
Risk Statements 20/21-36/38-43-52/53-22
Safety Statements 26-28-37/39-28B
WGK Germany 1
RTECS EJ5100000
3-10
TSCA Yes
HS Code 29109000
Hazardous Substances Data2425-79-8(Hazardous Substances Data)
ToxicityLD50 oral in rat: 1134mg/kg
MSDS Information
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1,4-Butanediol diglycidyl ether Usage And Synthesis
Description1,4-Butanediol diglycidyl ether is a reactive diluent in epoxy resins.
Chemical PropertiesClear yellow liquid
Uses
Uses1,4-Butanediol diglycidyl ether is used for preparing amylose, xylan and hydroxyethyl-cellulose, to cross link polyethylenimine which also serves as a hole-blocking layer in organic solar cells, to cross link hyaluronic acid into hydrogels and for the activation of soluble dextran polymers. It is the most commonly used homobifunctional epoxide compound
Production MethodsThe compound results from condensation of butanediol with epichlorohydrin followed by dehydrochlorination with caustic.
General DescriptionClear pale yellow liquid.
Air & Water ReactionsHygroscopic. Water soluble
Reactivity Profile1,4-Butanediol diglycidyl ether reacts with acids.
Fire Hazard1,4-Butanediol diglycidyl ether is combustible.
Flammability and ExplosibilityNonflammable
Contact allergensThis substance is a reactive diluent in epoxy resins
CarcinogenicityA2 year dermal cancer bioassay was conducted in CF1 mice at doses of 0%, 0.05%, and 0.2% in acetone . Treatment did not adversely affect survival, did not increase the incidence of skin tumors, and did not result in significant skin irritation. There were no statistically significant increases in incidence of any systemic tumors, except for lymphatic tumors in females. Because there was a high background incidence of this tumor type in CF1 mice used in the testing laboratory , there was no clear evidence of 1,4-BDDGE-induced carcinogenicity.
1,4-Butanediol diglycidyl ether Preparation Products And Raw materials
Raw materialsEpichlorohydrin-->1,4-Butanediol
1-BUTOXY-2-PROPANOL GLYCIDYL METHYL ETHER 1,3-BUTANEDIOL DIGLYCIDYL ETHER 1-PROPOXY-2-PROPANOL 1,4-BUTANEDIOL DIGLYCIDYL ETHER, (TETRAMETHYLENE GLYCOL DIGLYCIDYL ETHER) Butyl glycidyl ether 1,4-BUTYLENEGLYCOL DIGLYCIDYL ETHER = 1,4-BUTANEDIOL DIGLYCIDYL ETHER 1,4-Butanediol diglycidyl ether,commercial grade Ethylene glycol diglycidyl ether 3-Ethoxy-1-propanol N-PROPYL GLYCIDYL ETHER 1,2,3-PROPANETRIOL GLYCIDYL ETHER ETHYL GLYCIDYL ETHER Diglycidyl 1,2-cyclohexanedicarboxylate 1,4-Butanediol diglycidyl ether, acrylic acid polymer N-BUTANE BENZYL GLYCIDYL ETHER DIGLYCIDYL ETHER

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