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| | (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Basic information | | Reaction |
| Product Name: | (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE | | Synonyms: | (R)-TOL-SDP;(S)-(-)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE;(S)-7,7'-BIS[DI(P-METHYLPHENYL)PHOSPHINO]-1,1'-SPIROBIINDANE;(S)-TOL-SDP;(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE;(R)-(+)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane,min.97%(R)-Tol-SDP;(R)-(+)-7,7''-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2'',3,3''-TETRAHYDRO-1,1''-SPIROBIINDANE (R)-TOL-SDP;(R)7,7-BIS[DI(P-METHYLPHENYL)PHOSPHINO]-1,1-SPIROBIINDANE | | CAS: | 528521-87-1 | | MF: | C45H42P2 | | MW: | 644.76 | | EINECS: | | | Product Categories: | | | Mol File: | 528521-87-1.mol | ![(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Structure](CAS/GIF/528521-87-1.gif) |
| | (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Chemical Properties |
| Melting point | 150-152°C | | alpha | +212° (c 0.53, CH2Cl2) | | storage temp. | -20°C | | form | solid | | color | white | | Sensitive | air sensitive |
| | (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Usage And Synthesis |
| Reaction | Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
Ligands used for palladium-catalyzed asymmetric allylic alkylations.
| | Chemical Properties | Solid |
| | (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Preparation Products And Raw materials |
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