Ethyl cis-beta-cyanoacrylate

Ethyl cis-beta-cyanoacrylate Basic information
Product Name:Ethyl cis-beta-cyanoacrylate
Synonyms:ETHYL CIS-BETA-CYANOACRYLATE;ethyl cis-(β-cyano)acrylate;Ethyl (Z)-3-cyano-2-propenoate;Ethyl cis-(beta-cyano)acrylate 97%;Ethyl cis-(beta-cyano);(Z)-3-cyano-2-propenoic acid ethyl ester;(Z)-3-cyanoacrylic acid ethyl ester;Ethyl cis-β-cyanoacrylate
CAS:40594-97-6
MF:C6H7NO2
MW:125.13
EINECS:
Product Categories:AcrylateCarbonyl Compounds;Acrylic Monomers;C6 to C7;Esters;Monomers
Mol File:40594-97-6.mol
Ethyl cis-beta-cyanoacrylate Structure
Ethyl cis-beta-cyanoacrylate Chemical Properties
Melting point >300 °C(Solv: methanol (67-56-1); ethyl ether (60-29-7))
Boiling point 215 °C(lit.)
density 1.044 g/mL at 25 °C(lit.)
refractive index n20/D 1.4530(lit.)
Fp 225 °F
storage temp. 2-8°C
CAS DataBase Reference40594-97-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-51/53
Safety Statements 26-28-61
RIDADR UN 3082 9/PG 3
WGK Germany 2
MSDS Information
ProviderLanguage
SigmaAldrich English
Ethyl cis-beta-cyanoacrylate Usage And Synthesis
UsesEthyl cis-β-cyanoacrylate behaves as a dienophile in the synthesis of indeno[2,1-a]pyrrolo[3,4-c]carbazole lactam regioisomers via Diels-Alder reaction.
Synthesis Reference(s)The Journal of Organic Chemistry, 26, p. 6, 1961 DOI: 10.1021/jo01060a002
Ethyl cis-beta-cyanoacrylate Preparation Products And Raw materials
DIETHYL DICYANOFUMARATE, 97 ISONICOTINIC ACID, 3-CYANO-1,2-DIHYDRO-2-OXO-, ETHYL ESTER Ethanol Ethyl pyruvate Ethyl formate Ethyl cis-beta-cyanoacrylate 2-Hydroxyethyl methacrylate Ethylparaben ISOXADIFEN-ETHYL Ethyl acetate Cyano Acrylate 2-Hydroxyethyl acrylate Ethyl acrylate Ethyl N-cyanoethanimideate ETHYL 3-CYANO-2-HYDROXY-6-METHYLISONICOTINATE ETHYL 2-CYANOACRYLATE Ethyl methacrylate Ethyl cyanoacetate

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