CALMAGITE

CALMAGITE Basic information
Product Name:CALMAGITE
Synonyms:1-(1-HYDROXY-4-METHYL-2-PHENYLAZO)-2-NAPHTHOL-4-SULFONIC ACID;1-(1-HYDROXY-4-METHYL-2-PHENYLAZO)-2-NAPHTHOL-4-SULPHONIC ACID;TIMTEC-BB SBB008909;CALMAGIT Z. ANALYSE;CALMAGITE FREE ACID;CALMAGIT INDIKATOR FUER METALLTITRA-TION;CalmagiteIndicatorGrade;CalmagiteIndicatorGr
CAS:3147-14-6
MF:C17H14N2O5S
MW:358.37
EINECS:221-563-0
Product Categories:Azo;Organics;Analytical Chemistry;Azo Compounds;Chelating Reagents;Naphthylazo Compounds
Mol File:3147-14-6.mol
CALMAGITE Structure
CALMAGITE Chemical Properties
Melting point 330 °C (lit.)
density 0.989
storage temp. Store at RT.
solubility Solubility Soluble in water, ethanol
pka8.1(at 25℃)
form Powder
color Purple
OdorPhenolic odor
PH RangeRed (7.1) to blue (9.1)
Water Solubility Soluble in water.
λmax610nm
Merck 14,1718
BRN 708596
Stability:Stable. Incompatible with strong oxidizing agents.
Major ApplicationNanoparticles, cleaning microelectronic substrates, sensors, photographic materials, recording materials, water hardness measurement, indicator for calcium and magnesium, determination of vanadium, medical component, measuring magnesium in biological fluids, diagnosis of diseases caused by elemental imbalance, treatment of thrombocytopenia, Kurine analysis test strip
InChIKeyVBRNLOQCBCPPHL-VHEBQXMUSA-N
EPA Substance Registry System1-Naphthalenesulfonic acid, 3-hydroxy-4-[(2-hydroxy-5-methylphenyl)azo]- (3147-14-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA Yes
HS Code 29270000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
CALMAGITE Usage And Synthesis
Chemical Propertiesdark brown crystalline powder
UsesAs indicator in titration of Ca or Mg with EDTA.
UsesCalmagite is widely used in analytical chemistry as an indicator in the titration of calcium or magnesium with ethylenediaminetetraacetic acid (EDTA). It is also useful in the determination of magnesium in biological materials.
UsesUsed for the determination of magnesium in biological materials.
Purification MethodsA crude dye is extracted with anhydrous diethyl ether and forms red crystals from Me2CO. It gives a red colour in H2O at pH 7—9 and a blue colour at pH 9—11 which turns red on addition of Ca2+ or Mg2+ ions. [Lindstrom & Diehl Anal Chem 32 1123 1960]. Complexes with Ca, Mg and Th.
CALMAGITE Preparation Products And Raw materials
Calcium oxide calcium magnesium phosphate(CMP) ZINCON Starch Sodium hydrosulfide CALMAGITE 1-Amino-2-naphthol-4-sulfonic acid CALMAGITE TRIETHANOLAMMONIUM,calmagite triethanolamine Naphthionic acid CALMAGITE TRIETHANOLAMMONIUM SALT MAGNESIUM (CALMAGITE) KIT 2,2'-DIHYDROXYAZOBENZENE 2-PHENYLAZO-4-METHYLPHENOL 1-Naphthalenesulfonic acid Sudan I

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