TRIHEXYLSILANE

TRIHEXYLSILANE Basic information
Product Name:TRIHEXYLSILANE
Synonyms:Tri-n-hexylsilane ,95%;Trihexylsilicon;NSC 139856;TRIHEXYLSILANE;TRI-N-HEXYLSILANE;Silane, trihexyl-;rihexylsilicon;DK719
CAS:2929-52-4
MF:C18H40Si
MW:284.6
EINECS:220-893-2
Product Categories:Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Organometallic Reagents;Organosilicon;OthersSynthetic Reagents;Silanes
Mol File:2929-52-4.mol
TRIHEXYLSILANE Structure
TRIHEXYLSILANE Chemical Properties
Boiling point 160.5-161 °C (lit.)
density 0.799 g/mL at 25 °C (lit.)
refractive index n20/D 1.448(lit.)
Fp >230 °F
form clear liquid
color Colorless to Light yellow
Specific Gravity0.799
Hydrolytic Sensitivity3: reacts with aqueous base
EPA Substance Registry SystemSilane, trihexyl- (2929-52-4)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39-38-51-36/37
WGK Germany 1
TSCA Yes
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
TRIHEXYLSILANE Usage And Synthesis
Chemical PropertiesColorless liquid
UsesReactant for:
  • Enantioselective Si-H insertion
  • Regio- and stereoselective oxidation into silanols
  • Asymmetric carbenoid insertion of diazoacetates into the silicon-hydrogen bond
  • Hydrosilylation of carbon dioxide

Catalyst for hydrodefluorination leading to the synthesis of hydrocarbons
ApplicationReactivity similar to that of triethylsilane but has higher boiling point and produces a higher boiling by-product.
TRIHEXYLSILANE Preparation Products And Raw materials
TRI-N-PROPYLSILANE Triphenylsilyl chloride AMINOTRIPHENYLSILANE TRIPHENYLETHOXYSILANE TRIOCTYLSILANE TRI-N-PROPYLCHLOROSILANE TRI-N-HEXYLCHLOROSILANE Trimethylamine hydrochloride Triphenoxyvinylsilane TRIOCTYLBROMOSILANE METHYLTRI-N-OCTYLSILANE N-HEXYLSILANE METHYLTRI-N-DECYLSILANE TRIDODECYLBROMOSILANE Tri-N-hexylsilylamine methyltri-n-hexylsilane BIS(TRIHEXYLSILOXY)SILICON 2,3-NAPH- THALOCYANINE TRIDECYL SILANE

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