3-Bromophenylboronic acid

3-Bromophenylboronic acid Basic information
Product Name:3-Bromophenylboronic acid
Synonyms:RARECHEM AH PB 0076;AKOS BRN-0083;3-BROMOBENZENEBORONIC ACID;3-BROMOPHENYLBORONIC ACID;3-Bromophenylboronic;3-Bromophenylboronic Acid (contains varying amounts of Anhydride);3-Bromobenzeneboronic acid, 98+%;3-Bromophenylboronic acid,97%
CAS:89598-96-9
MF:C6H6BBrO2
MW:200.83
EINECS:677-281-7
Product Categories:Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;Boronate Ester;blocks;BoronicAcids;Bromides;Boric Acid;Boronic acids;Boronic Acid;Boronic Acids and Derivatives;Potassium Trifluoroborate;Aryl;Organoborons;B (Classes of Boron Compounds);Boronic Acids
Mol File:89598-96-9.mol
3-Bromophenylboronic acid Structure
3-Bromophenylboronic acid Chemical Properties
Melting point 164-168 °C (lit.)
Boiling point 330.5±44.0 °C(Predicted)
density 1.67±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
pka7.55±0.10(Predicted)
form Crystalline Powder
color White
BRN 3127104
CAS DataBase Reference89598-96-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 36/37/38-22
Safety Statements 37/39-26
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-Bromophenylboronic acid Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder
UsesReactant involved in a variety of organic reactions including:• ;Oxidative cross coupling1,2• ;Gold salt catalyzed homocoupling3• ;1,4-Addition reactions with α,β-unsaturated ketones4• ;Enantioselective addition reactions5• ;Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids6• ;C-H Functionalization of quinones7
Usessuzuki reaction
UsesReactant involved in a variety of organic reactions including:
  • Oxidative cross coupling
  • Gold salt catalyzed homocoupling
  • 1,4-Addition reactions with α,β-unsaturated ketones
  • Enantioselective addition reactions
  • Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids
  • C-H Functionalization of quinones
3-Bromophenylboronic acid Preparation Products And Raw materials
Preparation Products3-PHENOXYBROMOBENZENE-->3-Bromothioanisole-->3-Bromonitrobenzene-->3-Bromobenzophenone-->Quinoline, 2-(3-bromophenyl)--->2-(3-bromophenoxy)acetamide-->3-(3-BROMOPHENYL)-4'-METHOXYPROPIOPHENONE-->2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine
4-Bromobenzotrifluoride Ethyl 2-(Chlorosulfonyl)acetate Bromoxynil octanoate 1-Bromo-4-nitrobenzene Bromoxynil 4-BROMOPHENYLBORONIC ACID,P-BROMOPHENYLBORONIC ACID,4-Bromophenylboronic Acid (contains varying amounts of Anhydride) Phenylacetone Zinc borate Folic acid 3-Bromofluorobenzene Phenylboronic acid Glycine 2-Bromobenzaldehyde 1,2-Dibromobenzene phosphoric acid 1,4-Dibromobenzene Triphenylphosphine 4-Bromobenzaldehyde

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