ChemicalBook Product Catalog Chemical Reagents Organic reagents Silane TRIMETHYLSILYL BROMOACETATE

TRIMETHYLSILYL BROMOACETATE

TRIMETHYLSILYL BROMOACETATE Basic information
Product Name:TRIMETHYLSILYL BROMOACETATE
Synonyms:TRIMETHYLSILYL BROMOACETATE;BROMOACETIC ACID TRIMETHYLSILYL ESTER;Acetic acid, bromo-, trimethylsilyl ester;Trimethylsilyl bromoacetate, 98+%;2-Bromoacetic acid trimethylsilyl ester;TriMethylsilyl broMoacetate, 98% 5GR;Trimethylsilyl bromoacetate 98%;Trimethylsilyl Bromoacetate >
CAS:18291-80-0
MF:C5H11BrO2Si
MW:211.13
EINECS:242-165-3
Product Categories:Si (Classes of Silicon Compounds);Silyl Esters;Si-O Compounds;C2 to C5;Carbonyl Compounds;Esters
Mol File:18291-80-0.mol
TRIMETHYLSILYL BROMOACETATE Structure
TRIMETHYLSILYL BROMOACETATE Chemical Properties
Boiling point 57-58 °C/9 mmHg (lit.)
density 1.284 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
refractive index n20/D 1.442(lit.)
Fp 83 °F
storage temp. Flammables area
form clear liquid
color Colorless to Light yellow
Specific Gravity1.299
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Sensitive Moisture Sensitive
BRN 1927560
CAS DataBase Reference18291-80-0(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 10-34
Safety Statements 26-36/37/39-45
RIDADR UN 2920 8/PG 2
WGK Germany 3
F 10-19-21
TSCA No
HazardClass 8
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIMETHYLSILYL BROMOACETATE Usage And Synthesis
Chemical PropertiesClear slightly yellow liquid
UsesTrimethylsilyl bromoacetate has been used:
  • in the preparation of new imidazolium salts functionalized with the trimethylsilyl ester group
  • as alkylating agent in the synthesis of succinate fragment of pantocin B (antibiotic natural product)
  • in the synthesis of taxol derivatives tethered at C2′ and C-7 to glutamate and folate
TRIMETHYLSILYL BROMOACETATE Preparation Products And Raw materials
TRIMETHYLSILYL METHANESULFONATE TRIMETHYLSILYL(TRIMETHYLSILOXY)ACETATE ETHYL (METHYLTHIO)ACETATE BIS(TRIMETHYLSILYL) SULFATE TRIMETHYLSILYLBENZENESULFONATE trimethylsiloxytriethoxysilane TRIMETHYLSILYL TRIFLUOROACETATE TRIMETHYLSILYL CROTONATE TRIMETHYLOLPROPANE TRIS(3-MERCAPTOPROPIONATE) TRIMETHYLSILYL(TRIMETHYLSILYL)PROPYNOATE Silicon tetrahydride Bromoacetic acid Acetic acid
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