Methyl 3-hydroxybenzoate

Methyl 3-hydroxybenzoate Basic information
Uses
Product Name:Methyl 3-hydroxybenzoate
Synonyms:METHYL M-HYDROXYBENZOATE;3-HYDROXYBENZOIC ACID METHYL ESTER;AKOS BBB/380;AKOS BBS-00004297;M-HYDROXYBENZOIC ACID METHYL ESTER;RARECHEM AL BF 0067;Benzoic acid, 3-hydroxy-, methyl ester;METHYL 3-HYDROXYBENZOATE
CAS:19438-10-9
MF:C8H8O3
MW:152.15
EINECS:243-071-5
Product Categories:FINE Chemical & INTERMEDIATES;Aromatic Esters;Aromatics Compounds;Aromatics;C8 to C9;Carbonyl Compounds;Esters;bc0001
Mol File:19438-10-9.mol
Methyl 3-hydroxybenzoate Structure
Methyl 3-hydroxybenzoate Chemical Properties
Melting point 70-72 °C (lit.)
Boiling point 280-281 °C/709 mmHg (lit.)
density 1.1528
refractive index 1.4447 (estimate)
Fp 280-281°C/708mm
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in chloroform, dimetyl Sulfoxide,ethanol and methanol.
pka9.15±0.10(Predicted)
form Crystals
color Beige
BRN 2208129
LogP1.890
CAS DataBase Reference19438-10-9(CAS DataBase Reference)
NIST Chemistry Reference3-HO-C6H4-COOCH3(19438-10-9)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
HazardClass IRRITANT
HS Code 29163100
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Methyl 3-hydroxybenzoate Usage And Synthesis
UsesMethyl 3-Hydroxybenzoate can be used to increase the stability of agents to treat keratin material.
Chemical PropertiesWhite Solid
UsesMethyl 3-hydroxybenzoate is used in the preparation of 3-hydroxybenzene-1,2-dicarbaldehyde and O-methyl O-[3-methyl-4-(methylthio)phenyl]O-(3-methylcarboxyphenyl) phosphorothioate.
UsesMethyl 3-hydroxybenzoate has been used in synthesis of:
  • 3-hydroxybenzene-1,2-dicarbaldehyde
  • O-methyl O-[3-methyl-4-(methylthio)phenyl]O-(3-methylcarboxyphenyl) phosphorothioate
DefinitionChEBI: Methyl 3-hydroxybenzoate is a benzoate ester resulting from the formal condensation of the carboxy group of 3-hydroxybenzoic acid with methanol. It has a role as an antibacterial agent. It is a benzoate ester, a member of phenols and a methyl ester. It is functionally related to a 3-hydroxybenzoic acid.
Synthesis Reference(s)Synthetic Communications, 16, p. 331, 1986 DOI: 10.1080/00397918608076314
Methyl 3-hydroxybenzoate Preparation Products And Raw materials
Raw materialsMethylparaben
Preparation Products3-Hydroxybenzoic acid-->3-Cyanophenol-->METHYL 4-FORMYL-3-HYDROXYBENZOATE-->Methyl 3-methoxybenzoate-->3-BENZYLOXYBENZYL ALCOHOL-->3-ETHOXYBENZOIC ACID-->(-)-FENCHONE
Ethyl 3,4-dihydroxybenzoate Methylparaben 4-Hydroxybenzoic acid Salicylic acid Bensulfuron methyl 2'-Hydroxy-3-phenylpropiophenone Parathion-methyl (+)-Bicuculline Methyl 3-hydroxybenzoate METHYL-BETA-D-GALACTOPYRANOSIDE Methyl 3,4-dihydroxybenzoate Butylparaben Ellagic acid Kresoxim-methyl Thiophanate-methyl Methyl acrylate Octyl gallate Ethyl 3-hydroxybenzoate

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