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(Z)-beta-damascone

(Z)-beta-damascone Basic information
Product Name:(Z)-beta-damascone
Synonyms:DAMASCONE (BETA);DAMASCONE;FEMA 3243;1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-,(Z)-2-Buten-1-one;1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-cis-2-Buten-1-one;(Z)-1-(2,6,6-trimethylcyclohexen-1-yl)but-2-en-1-one;4-Acetoxy-β;(Z)-1-(2,6,6-Trimethylcyclohexen-1-yl)-2-buten-1-one
CAS:23726-92-3
MF:C13H20O
MW:192.3
EINECS:245-842-1
Product Categories:
Mol File:23726-92-3.mol
(Z)-beta-damascone Structure
(Z)-beta-damascone Chemical Properties
Boiling point 271.2±10.0 °C(Predicted)
density 0.934 g/mL at 20 °C(lit.)
FEMA 3243 | 1-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-2-BUTEN-1-ONE
refractive index n20/D 1.498
storage temp. 2-8°C
Odorat 1.00 % in dipropylene glycol. fruity floral blackcurrant tobacco
Odor Typefruity
Water Solubility 192.3mg/L(temperature not stated)
JECFA Number384
Stability:Light Sensitive
LogP3.312 (est)
EPA Substance Registry System2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2Z)- (23726-92-3)
Safety Information
Hazard Codes Xi
Risk Statements 43
Safety Statements 36/37
WGK Germany 2
RTECS EN0340000
F 10-23
MSDS Information
ProviderLanguage
SigmaAldrich English
(Z)-beta-damascone Usage And Synthesis
Chemical Properties(Z)-beta-damascone is a colorless to pale yellow liquid with floral, fruity and rose-like aromas, and exists in apple, raspberry oil, etc.
UsesA food spice that can be used to formulate rose essence.
Synthesis(Z)-beta-damascone can be synthesized by the reaction of ethyl crocinate and allyl lithium, followed by catalytic isomerization.
(Z)-beta-damascone Preparation Products And Raw materials
Raw materials2-N-BUTOXYETHYL METHACRYLATE-->DAMASCONE-->PROPYNYLLITHIUM
Damascenone (3E)-4-[(R)-2,2,6-Trimethyl-5-cyclohexen-1-yl]-3-buten-2-one semicarbazone Dehydroepiandrosterone Cyclohexene Tiglic aldehyde 4-[3-(β-D-Glucopyranosyloxy)-4-hydroxy-2,6,6-trimethyl-1-cyclohexen-1-yl]-3-buten-2-one Neosperidin dihydrochalcone Epiandrosterone acetate Tetrahydro-4H-pyran-4-one (Z)-beta-damascone 4-(2,6,6-Trimethyl-1-cyclohexen-1-yl)-3-buten-2-one semicarbazone PIPERONYL METHYL KETONE 1-Tetralone Methyl vinyl ketone 1-(2,4,4-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one 2-Cyclohexen-1-one Tetrahydrothiophen-3-one Cyclohexene oxide
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