Bifenox

Bifenox Basic information
Product Name:Bifenox
Synonyms:METHYL 5-(2,4-DICHLOROPHENOXY)-2-NITROBENZOATE;MC-4379;FOX;BIFENOX;MODOWN;bifenox (bsi,iso,ansi,wssa);MC 79;Plodown
CAS:42576-02-3
MF:C14H9Cl2NO5
MW:342.13
EINECS:255-894-7
Product Categories:Aromatics;Intermediates & Fine Chemicals;Alphabetic;B;BI - BZPesticides&Metabolites;Pharmaceuticals;Diphenyl ether;Herbicides
Mol File:42576-02-3.mol
Bifenox Structure
Bifenox Chemical Properties
Melting point 84-86°
Boiling point 421.0±45.0 °C(Predicted)
density 1.5715 (rough estimate)
refractive index 1.7350 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form neat
Water Solubility 0.5mg/L(temperature not stated)
Merck 13,1214
BRN 2170169
LogP4.480
CAS DataBase Reference42576-02-3(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate(42576-02-3)
EPA Substance Registry SystemBifenox (42576-02-3)
Safety Information
Hazard Codes N
Risk Statements 50/53
Safety Statements 60-61
RIDADR UN 3077 9/PG 3
WGK Germany 2
RTECS DG7890000
HS Code 29189900
Hazardous Substances Data42576-02-3(Hazardous Substances Data)
ToxicityLD50 orally in rats, mice: >6400, 4556 mg/kg; LC50 in pheasants, wild ducks: >5000 ppm (Kruger)
MSDS Information
ProviderLanguage
Bifenox English
Bifenox Usage And Synthesis
UsesHerbicide.
UsesSelective preemergence or postemergence herbicide used to effectively control a wide variety of broad-leaved weeds (such as bindweed, jimsonweed, kochia, mustards, pigweeds, sesbania, smartweed and velvet-leaf) in tolerant crops (corn, grain sorghum, maize, rice and soybeans).
DefinitionChEBI: MC-4379 is a nitrobenzoic acid.
Agricultural UsesHerbicide: Used to control a variety of broadleaf weeds and grasses in legumes such as soybeans and peanuts, and post-emergent weed control in wheat, barley and sugar beets. Not currently registered in the U.S. However, it is used in 21 European countries and there are 27 global suppliers.
Trade nameALIBI®; FOX®; MODOWN®[C]; MC- 4379®; SABINE®
Environmental FateSoil. Bifenox degrades in soil forming 5-(2,4-dichlorophenoxy)-2-nitrobenzoic acid and methyl 5-(2,4-dichlorophenoxy)anthranilate (Hartley and Kidd, 1987; Smith 1988). The average half-life in soils is 7–14 days (Hartley and Kidd, 1987; Humburg et al., 1989)
Plant. Rapidly undergoes ring hydroxylation and subsequent conjugation in rice plants (Ashton and Monaco, 1991).
Photolytic. The UV photolysis (λ = 300 nm) of bifenox in various solvents was studied by Ruzo et al. (1980). In water, 2,4-dichloro-3′-(carboxymethyl)-4′-hydroxydiphenyl ether and 2,4-dichloro-3′-(carboxymethyl)-4′-aminodiphenyl ether were identi

Methylparaben 4-(2-Chlorophenoxy)benzamide Bensulfuron methyl Parathion-methyl Bifenox S-Carboxymethyl-L-cysteine Difenoconazole Diethatylethyl 2-Amino-5-methoxybenzoic acid Benzofluorfen Thiophanate-methyl 4-Amino-4'-chlorodiphenyl ether Methyl acrylate Methyl methacrylate Methyl formate Methyl acetate Methyl bromide 1,3-Dinitrobenzene

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