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| | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Basic information | | Reaction |
| Product Name: | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE | | Synonyms: | BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON;1,1'-Bis(di-t-butylphosphino)ferrocene,min.98%;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE;1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98%;1,1'-Bis(di-tert-butylphosphino)ferrocene ,98%;1,1'-Bis(di-tert-butylphosphin;98% DtBPF;1,1'-Bis(di-tert-butylphosphiNA)ferrocene | | CAS: | 84680-95-5 | | MF: | C26H44FeP210* | | MW: | 474.42 | | EINECS: | 626-167-5 | | Product Categories: | Achiral Phosphine;Aryl Phosphine;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Polydentate Phosphine Ligands | | Mol File: | 84680-95-5.mol |  |
| | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Chemical Properties |
| Melting point | 181-182°C (dec.) | | storage temp. | Inert atmosphere,Room Temperature | | form | crystal | | color | orange to red | | Water Solubility | Insoluble in water. | | InChIKey | FPLSJBJGQLJLSV-UHFFFAOYSA-N |
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ALFA
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| | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Usage And Synthesis |
| Reaction |
- Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
- Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
- Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
- Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
- Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
- Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
- Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
- Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
- Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.
| | Uses | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand. | | Uses | The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene. |
| | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Preparation Products And Raw materials |
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