1,3,3-Trimethyl-2-methyleneindoline

1,3,3-Trimethyl-2-methyleneindoline Basic information
Product Name:1,3,3-Trimethyl-2-methyleneindoline
Synonyms:FISCHER BASE;FISCHERS BASE;FISCHER'S BASE;1,3,3-TRIMETHYL-2-METHYLENEINDOINE;1,3,3-TRIMETHYL-2-METHYLENE INDOLENINE;1,3,3'-TRIMETHYL-2-METHYLENEINDOLINE;1,3,3-TRIMETHYL-2-METHYLENEINDOLINE;2-METHYLENE-1,3,3-TRIMETHYLINDOLINE
CAS:118-12-7
MF:C12H15N
MW:173.25
EINECS:204-235-1
Product Categories:Indole;Intermediates of Dyes and Pigments
Mol File:118-12-7.mol
1,3,3-Trimethyl-2-methyleneindoline Structure
1,3,3-Trimethyl-2-methyleneindoline Chemical Properties
Melting point -8 °C
Boiling point 248 °C (lit.)
density 0.979 g/mL at 25 °C (lit.)
refractive index n20/D 1.577(lit.)
Fp 215 °F
storage temp. Store below +30°C.
solubility negligible
pka2.19±0.40(Predicted)
form liquid
color red
Specific Gravity0.98
Water Solubility negligible
BRN 131162
CAS DataBase Reference118-12-7(CAS DataBase Reference)
NIST Chemistry Reference1H-Indole, 2,3-dihydro-1,3,3-trimethyl-2-methylene-(118-12-7)
EPA Substance Registry System1H-Indole, 2,3-dihydro-1,3,3-trimethyl-2-methylene- (118-12-7)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-38-50/53
Safety Statements 28-60-61-57-37
RIDADR UN 3082 9/PG 3
WGK Germany 2
RTECS NM1926500
23
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29339990
MSDS Information
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1,3,3-Trimethyl-2-methyleneindoline English
SigmaAldrich English
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ALFA English
1,3,3-Trimethyl-2-methyleneindoline Usage And Synthesis
Chemical Propertiesclear red liquid
UsesReactant for:
  • Cycloaddition reactions
  • Preparation of red photochromic dyes
  • Synthesis of photochromic homopolymers via ring-opening metathesis polymerization
AURORA KA-4741 1,1',3,3,3',3'-HEXAMETHYL-4,4',5,5'-DI-BENZO-2,2'-INDOTRICARBOCYANINE PERCHLORATE 5-CHLORO-1,3,3-TRIMETHYL-2-METHYLENEINDOLINE 1,3,3-Trimethyl-2-(formylmethylene)indoline IR-144 AURORA KA-3494 2-(3-(3,3-DIMETHYL-4-NITRO-1-(3-SULFOPROPYL)-1H-2(3H)-INDOLIDENE)-1-PROPENYL)-3,3-DIMETHYL-4-NITRO-1-(3-SULFOPROPYL)-3H-INDOLIUM HYDROXIDE, INNER SALT 1,1',3,3,3',3'-HEXAMETHYLINDOTRICARBOCYANINE PERCHLORATE AURORA KA-3495 Hexacyanine 2 1,1',3,3,3',3'-HEXAMETHYLINDOTRICARBOCYANINE IODIDE 2-METHYLENE-5-NITRO-1,3,3-TRIMETHYLINDOLINE AURORA KA-3492 AURORA KA-4744 1,3,3'-TRIMETHYL-2-METHYLENEINDOLINE ALDEHYDE 2-(7-(3,3-DIMETHYL-1-PHENYL-1H-2(3H)-INDOLIDENE)-1,3,5-HEPTATRIENYL)-3,3-DIMETHYL-1-PHENYL-3H-INDOLIUM PERCHLORATE 5-CHLORO-1,3,3-TRIMETHYL-2-METHYLENEINDOLINE 2-(7-(1,1-DIMETHYL-3-PHENYL-1H-2(3H)-BENZINDOLIDENE)-1,3,5-HEPTATRIENYL)-1,1-DIMETHYL-3-PHENYL-1H-BENZINDOLIUM PERCHLORATE

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