6-METHOXY-2-BENZOXAZOLINONE

6-METHOXY-2-BENZOXAZOLINONE Basic information
Product Name:6-METHOXY-2-BENZOXAZOLINONE
Synonyms:JRH-04701, 6-Methoxybenzo[d]oxazol-2(3H)-one, 97%;6-Methoxy-2,3-dihydrobenzoxazole-2-one;6-Methoxybenzoxazol-2(3H)-one;6-methoxy-3H-1,3-benzoxazol-2-one;6-Methoxy-2-benzoxazoline;6-Methoxy-3H-benzoxazol-2-one;6-Methoxy benzoxazol-2-one;6-METHOXY-2-BENZOXAZOLININE
CAS:532-91-2
MF:C8H7NO3
MW:165.15
EINECS:
Product Categories:Building Blocks;Chemical Synthesis;Building Blocks;Heterocyclic Building Blocks;Oxazoles;Heterocyclic Building Blocks;Heterocyclic Compounds;Oxazolines/Oxazolidines
Mol File:532-91-2.mol
6-METHOXY-2-BENZOXAZOLINONE Structure
6-METHOXY-2-BENZOXAZOLINONE Chemical Properties
Melting point 151-156 °C(lit.)
Boiling point 292.97°C (rough estimate)
density 1.3450 (rough estimate)
refractive index 1.5468 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Acetone, Dichloromethane, Methanol, Tetrahydrofuran
pka8.73±0.70(Predicted)
form Solid
color light tan
BRN 141041
Safety Information
Safety Statements 22-24/25
WGK Germany 3
RTECS DM5275200
HS Code 2934999090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
6-METHOXY-2-BENZOXAZOLINONE Usage And Synthesis
Uses6-Methoxybenzoxazolinone is an intermdiate in the synthesis of DIMBOA-4-O-β-D-glucuronide which is a metabolite of DIMBOA which acts as an antifungal and antialgal agent in crops. The benzoxazinone group within the structure allows for these effects.
DefinitionChEBI: Coixol is a benzoxazole.
Synthesis Reference(s)Synthetic Communications, 23, p. 343, 1993 DOI: 10.1080/00397919308009786
General Description6-Methoxy-2-benzoxazolinone (MBOA) is obtained by reacting 2-amino-5-methoxyphenol hydrochloride with urea. MOBA is a naturally occurring auxin-inhibiting substance present in maize shoots.
6-METHOXY-2-BENZOXAZOLINONE Preparation Products And Raw materials
Daurinoline Xanthiazone veratramine VERATRIDINE Xanthiside L-Hyoscyamine daurisoline 2-[2-(Methylamino)benzoyl]-3,4-dihydro-β-carboline-1(2H)-one VERATRINE menisdaurin 6-BENZYLOXY-2-BENZOXAZOLINONE 97 6-METHOXY-2-BENZOXAZOLINONE 2-Benzoxazolinone 6-HYDROXY-2-BENZOXAZOLINONE 97

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