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Methyltriphenylphosphonium iodide

Methyltriphenylphosphonium iodide Basic information
Product Name:Methyltriphenylphosphonium iodide
Synonyms:METHYLTRIPHENYLPHOSPHONIUM IODIDE;MPJ;TRIPHENYLMETHYL PHOSPHONIUM IODIDE;Methyl triphenylphosphonium iodide, 98+%;METHYLTRIPHENYPHOSPHONIUMIODIDE;Methyltriphenylphosphanium iodide;Phosphonium, methyltriphenyl-, iodide;Triphenylmethylphosphine iodide
CAS:2065-66-9
MF:C19H18IP
MW:404.22
EINECS:218-178-5
Product Categories:C-C Bond Formation;Olefination;Wittig Reagents;Phosphonium Compounds;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Wittig Reaction
Mol File:2065-66-9.mol
Methyltriphenylphosphonium iodide Structure
Methyltriphenylphosphonium iodide Chemical Properties
Melting point 183-185 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder
color White to light yellow
Water Solubility SOLUBLE
Sensitive Light Sensitive & Hygroscopic
InChIInChI=1S/C19H18P.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
InChIKeyJNMIXMFEVJHFNY-UHFFFAOYSA-M
SMILES[P+](C)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[I-]
CAS DataBase Reference2065-66-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,T
Risk Statements 36/37/38-25
Safety Statements 26-36-45-37/39-28A
RIDADR UN3464
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29319090
MSDS Information
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Methyltriphenylphosphonium iodide English
SigmaAldrich English
ACROS English
ALFA English
Methyltriphenylphosphonium iodide Usage And Synthesis
Chemical PropertiesWHITE TO LIGHT YELLOW POWDER
UsesMethyltriphenylphosphonium iodide is as a reactant for synthesis of triphenylamine-based dyes and polyolefinic aromatic molecules with pyrene for use in dye-sensitized solar cells. Used as ligand in coupling reaction. It is also used as a precursor to a Wittig reagent.
Usessuzuki reaction
Methyltriphenylphosphonium iodide Preparation Products And Raw materials
Preparation Products4-Chloro-alpha-methylstyrene-->4-Fluorostyrene-->4-Chlorostyrene-->4-Hydroxystyrene-->alpha-cyclopropylstyrene-->Cyclohexene, 2-ethenyl-1,3,3-trimethyl--->4-IODOSTYRENE-->2-Hydroxystyrene-->2-METHYL-6-VINYLPYRIDINE-->1,3-DIVINYLBENZENE-->METHYLENECYCLOPENTANE-->(2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene-->1,3-dichloro-5-(3,3,3-trifluoroprop-1-en-2-yl)benzene-->1-Fluoro-4-(1-methylethenyl)benzene-->1-Cbz-4-methylene-piperidine-->3-METHYLENECYCLOBUTANECARBOXYLIC ACID-->METHYL 4-VINYLBENZOATE-->3-Bromostyrene
TRIS(4-METHOXYPHENYL)(METHYL)PHOSPHONIUM IODIDE Methyl METHYLTRIPHENYLPHOSPHONIUM IODIDE POLY& METHYLTRIPHENYLPHOSPHONIUM IODIDE, [METHYL-14C] PHOSPHONIUM IODIDE TRIS(4-CHLOROPHENYL)(METHYL)PHOSPHONIUM IODIDE (CHLOROMETHYL)TRIPHENYLPHOSPHONIUM IODIDE (METHYL-D3)TRIPHENYLPHOSPHONIUM IODIDE METHYLTRIPHENYLPHOSPHONIUM IODIDE, POLYMER-BOUND BENZYLTRIPHENYLPHOSPHONIUM IODIDE Kresoxim-methyl (METHYL-13C)TRIPHENYLPHOSPHONIUM IODIDE TRIPHENYLMETHYL PHOSPHONIUM IODIDE TETRAPHENYLPHOSPHONIUM IODIDE Thiophanate-methyl (cyclohexylmethyl) triphenylphosphonium iodide [5-(ETHYLTHIO)-2-PHENYL-1,3-THIAZOL-4-YL](TRIPHENYL)PHOSPHONIUM IODIDE E-(2-ETHOXY-PROPENYL)-TRIPHENYL-PHOSPHONIUM IODIDE SALT
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