Dichlorodiethylsilane

Dichlorodiethylsilane Basic information
Product Name:Dichlorodiethylsilane
Synonyms:Diethyldichlorosilane(Dichlorodiethylsilane);DIETHYLSILICIUMDICHLORID;DIETHYLDICHLOROSILANE;DICHLORODIETHYLSILANE;dichlorodiethyl-silan;Diethyldichlorosilicon;Silane, dichlorodiethyl-;silane,dichlorodiethyl-
CAS:1719-53-5
MF:C4H10Cl2Si
MW:157.11
EINECS:217-005-0
Product Categories:Si-Cl Compounds;Silylation (GC Derivatizing Reagents);Protecting and Derivatizing Reagents;Protection and Derivatization;Silicon-Based;Analytical Chemistry;Dichlorosilanes;Dichlorosilanes (for Polysilanes);Functional Materials;GC Derivatizing Reagents;Pentafluorophenylsilylation, etc. (GC Derivatizing Reagents);Reagent for High-Performance Polymer Research;Si (Classes of Silicon Compounds)
Mol File:1719-53-5.mol
Dichlorodiethylsilane Structure
Dichlorodiethylsilane Chemical Properties
Melting point -96 °C
Boiling point 125-131 °C(lit.)
density 1.05 g/mL at 25 °C(lit.)
refractive index n20/D 1.43(lit.)
Fp 83 °F
storage temp. Flammables area
form liquid
Specific Gravity1.05
color Colorless to Almost colorless
Water Solubility insoluble
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Moisture Sensitive
BRN 605313
Stability:Stable. Incompatible with strong oxidizing agents. May decompose upon exposure to water or moisture.
CAS DataBase Reference1719-53-5(CAS DataBase Reference)
NIST Chemistry ReferenceDichlorodiethylsilane(1719-53-5)
EPA Substance Registry SystemDiethyldichlorosilane (1719-53-5)
Safety Information
Hazard Codes F,C
Risk Statements 11-14-34-37-10
Safety Statements 26-36/37/39-45-25-16-43
RIDADR UN 1767 8/PG 2
WGK Germany 1
RTECS VV3060000
10-21
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29310095
Hazardous Substances Data1719-53-5(Hazardous Substances Data)
Toxicityrat,LDLo,intraperitoneal,100mg/kg (100mg/kg),Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 332, 1948.
MSDS Information
ProviderLanguage
Diethyldichlorosilane English
SigmaAldrich English
ACROS English
ALFA English
Dichlorodiethylsilane Usage And Synthesis
Chemical Propertiescolourless liquid
UsesUsed primarily as an intermediate for silicones.
UsesDichlorodiethylsilane is used in ethchlorvynol assay. It is used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuffs.
Production MethodsProduced by reaction of powdered silicon and ethyl chloride at 300℃, in the presence of copper powder.
General DescriptionA colorless liquid with a pungent odor. Flash point 77°F. Corrosive to metals and tissue. Vapors are heavier than air.
Reactivity ProfileChlorosilanes, such as Dichlorodiethylsilane, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.
Health HazardTOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Safety ProfilePoison by intraperitoneal route. Moderately toxic by ingestion. Corrosive to tissue. Dangerous fire hazard when exposed to heat, flame, or oxidzers. Can react vigorously with oxidizing materials. To fight fire, use foam, Con, dry chemical. When heated to decomposition or in reaction with water or steam it emits toxic and corrosive fumes of Cl-. See also CHLOROSILANES.
Dichlorodiethylsilane Preparation Products And Raw materials
Preparation ProductsEthyldichlorosilane-->Silane, diethylbis(trifluoroethenyl)-
DICYCLOHEXYLDICHLOROSILANE ALLYLHEXYLDICHLOROSILANE CYCLOTETRAMETHYLENEDICHLOROSILANE DI-N-BUTYLDICHLOROSILANE BIS(3-CHLOROPROPYL)DICHLOROSILANE DICHLORODI-N-PENTYLSILANE N-PROPYL(3-CHLOROPROPYL)DICHLOROSILANE BIS(CYANOPROPYL)DICHLOROSILANE CYCLOPENTAMETHYLENEDICHLOROSILANE BIS(3,3,3-TRIFLUOROPROPYL)DICHLOROSILANE DI-TERT-BUTYLDICHLOROSILANE ALLYL(CHLOROPROPYL)DICHLOROSILANE ALLYL[(2-CYCLOHEXENYL-2-ETHYL)]-DICHLOROSILANE ETHYLSILANE Ethyldichlorosilane DI-N-HEXYLDICHLOROSILANE PHENYLDICHLOROSILANE DIALLYLDICHLOROSILANE

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