3-CHLOROTHIOPHENE

3-CHLOROTHIOPHENE Basic information
Product Name:3-CHLOROTHIOPHENE
Synonyms:3-CHLOROTHIOPHENE;3-thienyl chloride;3-Chlorothiophene,98%;3-Chlorothiophene, 98%, May contain up to 2% DiMethyl forMaMide;3-Chlorothiophene, 98% 5GR;3-Chlorothiophene,98%,maycontainupto2%DMF;3-Chlorothiophene 98%;Thiophene, 3-chloro-
CAS:17249-80-8
MF:C4H3ClS
MW:118.58
EINECS:605-636-8
Product Categories:Heterocycle-oher series;Halogenated Heterocycles;Functional Materials;Reagents for Conducting Polymer Research;Heterocyclic Building Blocks;ThiophenesBuilding Blocks;Thiophenes;Thiophene&Benzothiophene;Thiophens;Thiophene Derivatives (for Conduting Polymer Research);Thiophen
Mol File:17249-80-8.mol
3-CHLOROTHIOPHENE Structure
3-CHLOROTHIOPHENE Chemical Properties
Melting point -62 °C
Boiling point 137-139 °C(lit.)
density 1.276 g/mL at 25 °C(lit.)
refractive index n20/D 1.553(lit.)
Fp 99 °F
storage temp. Keep in dark place,Sealed in dry,2-8°C
form Liquid
Specific Gravity1.276
color Clear colorless to light yellow
BRN 105255
Exposure limitsACGIH: TWA 5 ppm (Skin)
OSHA: TWA 10 ppm(30 mg/m3)
NIOSH: IDLH 500 ppm; TWA 10 ppm(30 mg/m3)
InChIKeyQUBJDMPBDURTJT-UHFFFAOYSA-N
CAS DataBase Reference17249-80-8(CAS DataBase Reference)
Safety Information
Hazard Codes T,F,Xi
Risk Statements 61-10-36-36/37/38-41-37/38-22
Safety Statements 53-16-26-45-36-7/9-37/39-39
RIDADR UN 1993 3/PG 3
WGK Germany -
Hazard Note Irritant
HazardClass 3
PackingGroup III
HS Code 29339900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-CHLOROTHIOPHENE Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
Uses3-Chlorothiophene was used in the synthesis of poly(3-chlorothiophene) films by direct oxidation in mixed electrolytes of boron trifluoride diethyl etherate and trifluroacetic acid.
Synthesis Reference(s)Journal of Heterocyclic Chemistry, 14, p. 281, 1977 DOI: 10.1002/jhet.5570140224
General DescriptionElectrochemical homopolymerization of 3-chlorothiophene and copolymerization with 3-methylthiophene in ionic liquid has been investigated by potentiodynamic and galvanostat methods.
3-CHLOROTHIOPHENE Preparation Products And Raw materials
Preparation ProductsTenoxicam-->3-Chlorothiophene-2-carboxylic acid-->2-ACETYL-3-CHLOROTHIOPHENE-->3-Chlorothiophene-2-carbonyl chloride-->3-Hexylthiophene-->2-Bromo-3-chlorothiophene-->2-ACETYL-4-CHLOROTHIOPHENE-->METHYL 3-THIOPHENECARBOXYLATE 97
METHYL 3-CHLORO-4-METHYLTHIOPHENE-2-CARBOXYLATE 3-CHLORO-BENZO[B]THIOPHENE-2-CARBOXYLIC ACID HYDRAZIDE 2-Bromo-3-chlorothiophene 2,3-DICHLOROTHIOPHENE 3-CHLOROBENZO[B]THIOPHENE-2-CARBOXAMIDE 3-CHLOROTHIOPHENE 3-CHLORO-4-METHYLTHIOPHENE-2-CARBOHYDRAZIDE METHYL 3-CHLORO-4-(METHYLSULFONYL)THIOPHENE-2-CARBOXYLATE 3-CHLOROBENZO[B]THIOPHENE-2-CARBONYL CHLORIDE 3-CHLORO-4-(METHYLSULFONYL)THIOPHENE-2-CARBOXYLIC ACID METHYL 3-CHLOROBENZO[B]THIOPHENE-2-CARBOXYLATE 3-CHLOROTHIOPHENE-2-CARBOXYLIC ACID 3-CHLOROTHIOPHENE-2-CARBOXYLIC ACID METHYL ESTER 3-CHLOROTHIOPHENE-2-CARBOXAMIDE 3-CHLOROTHIOPHENE-2-CARBONYL CHLORIDE METHYL 3-CHLORO-4-(ISOPROPYLSULFONYL)THIOPHENE-2-CARBOXYLATE 2,3-Dichlorothiophene-5-sulphonyl chloride TETRACHLOROTHIOPHENE

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