ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic palladium Bis(tricyclohexylphosphine)palladium(II) Dichloride

Bis(tricyclohexylphosphine)palladium(II) Dichloride

Bis(tricyclohexylphosphine)palladium(II) Dichloride Basic information
Product Name:Bis(tricyclohexylphosphine)palladium(II) Dichloride
Synonyms:TRANS-DICHLOROBIS-(TRICYCLOHEXYLPHOSPHINE)-PALLADIUM;TRANS-DICHLOROBIS(TRICYCLOHEXYLPHOSPHINE)PALLADIUM(II);trans-Dichlorobis(tricyclohexylphosphine)palladium(II),99%;dichlorobis(tricyclohexylphophine)palladium (ii);Dichlorobis(tricyclohexylphosphine)palladium(II), Pd 14.4%;BIS(TRICYCLOHEXYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;DICHLOROBIS(TRICYCLOHEXYLPHOSPHINE)PALLADIUM(II);dichloropalladium,tricyclohexylphosphane
CAS:29934-17-6
MF:C36H66Cl2P2Pd
MW:738.18
EINECS:681-696-9
Product Categories:Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;metal-phosphine complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Palladium;Pd
Mol File:29934-17-6.mol
Bis(tricyclohexylphosphine)palladium(II) Dichloride Structure
Bis(tricyclohexylphosphine)palladium(II) Dichloride Chemical Properties
Melting point 270 °C (dec.)(lit.)
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Powder
color Yellow
Water Solubility Moderately soluble in dichloromethane and chloroform. Sparingly soluble in benzene and toluene. Insoluble in water, alcohols, acetone, diethyl ether, andhexanes.
InChIKeyKHXRPVIZRSHDNN-UHFFFAOYSA-N
CAS DataBase Reference29934-17-6
Safety Information
Risk Statements 22-36/37/38
Safety Statements 15-22-36/37/39-37/39-26
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Bis(tricyclohexylphosphine)palladium(II) Dichloride Usage And Synthesis
Chemical PropertiesYellow powder
Usessuzuki reaction
UsesIt is used as catalyst for C-C and C-N coupling reaction. It is used in the homogeneous carbonylation of chloroarenes under mild conditions.
UsesApplication Guide for Palladium Catalyzed Cross-Coupling Reactions
General DescriptionDichlorobis(tricyclohexylphosphine)palladium(II) is widely employed as catalyst precursor in various carbon-carbon and carbon-heteroatom bond forming reactions.
SynthesisBis(tricyclohexylphosphine)palladium(II) Dichloride is prepared by reacting  Tricyclohexyl phosphine with Palladium chloride refluxed in acetone for 3h.
Bis(tricyclohexylphosphine)palladium(II) Dichloride Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Dichloromethane-->Toluene-->Acetonitrile-->Magnesium-->Phosphorus trichloride-->Palladium chloride-->Bromocyclohexane-->Tricyclohexyl phosphine
BIS(TERT-BUTYLIMINO)BIS(DIMETHYLAMINO)& Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis[Tris(2-methylphenyl)phosphine]palladium Tetrakis(triphenylphosphine)platinum TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Bis(benzonitrile)palladium chloride Bis(tricyclohexylphosphine)palladium(0) Bis(tri-tert-butylphosphine)palladium(0) Bis(triphenylphosphinepalladium) acetate Dichloro(1,5-cyclooctadiene)platinum(II) Bis(triphenylphosphine)palladium(II) chloride CYCLOHEXYLPHOSPHINE TRIISOPROPYLPHOSPHINE DICYCLOHEXYLPHOSPHINE Bis(tricyclohexylphosphine)palladium(II) Dichloride TRIHEXYLPHOSPHINE Palladium chloride Tricyclohexyl phosphine
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