3,6-Dibromocarbazole

3,6-Dibromocarbazole Basic information
Product Name:3,6-Dibromocarbazole
Synonyms:3,6-DIBROMOCARBAZOLE, TECH., 90%;3,6-Dibromo-9H-carbazole;3,6-DIBROMOCARBAZOLE;3,6-DibroMocarbazole,3,6-DibroMo-9H-carbazole;9H-Carbazole,3,6-dibroMo-;3,6-DibroMocarbazole (3,6-DBC);DibroMocarbazole;3,6-Dibromocarbazole,99%
CAS:6825-20-3
MF:C12H7Br2N
MW:325
EINECS:202-205-2
Product Categories:Carbazole Series;organic chemicals and derivatives/others;CarbazolesHeterocyclic Building Blocks;Building Blocks;Halogenated Heterocycles;OLED;Carbazoles;Carbazoles (for Conduting Polymer Research);Functional Materials;Reagents for Conducting Polymer Research;Heterocyclic Building Blocks;Apoptosis Inhibitors;OLED materials,pharm chemical,electronic;OLED, OLED materials,pharm chemical.;carbazole;bc0001
Mol File:6825-20-3.mol
3,6-Dibromocarbazole Structure
3,6-Dibromocarbazole Chemical Properties
Melting point 204-206 °C (lit.)
Boiling point 459.0±25.0 °C(Predicted)
density 1.930±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in benzene, chloroform
pka15.47±0.30(Predicted)
form Crystalline Powder
color Tan
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKeyFIHILUSWISKVSR-UHFFFAOYSA-N
CAS DataBase Reference6825-20-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
3,6-Dibromocarbazole Usage And Synthesis
Chemical Propertiestan to light green powder
Uses3,6-Dibromocarbazole is used as a pharmaceutical intermediate, and also an important intermediate of synthesizing optoelectronic materials. It has been used in the preparation of N-(2-hydroxyethyl)-3,6-dibromocarbazole.
General DescriptionLithiation of 3,6-dibromocarbazole with n-butyllithium has been studied.
Synthesis3, 6-dibromocarbazole is synthesized with three methods, such as N-bromosuccinimide method, liquid bromine method and silica gel method. But now main method for synthesis is silica gel method. The main raw materials used in the synthesis include carbazole, N-bromosuccinimide, solvent methylene chloride, catalyst silica gel, and the yield could reach 89.5%.
3,6-Dibromocarbazole Preparation Products And Raw materials
Preparation Products3,6-Dibromo-9-ethylcarbazole-->P7C3-A20-->3,6-DIPHENYL-9H-CARBAZOLE -->TIMTEC-BB SBB006353
(+)-1-(3,6-DIBROMOCARBAZOL-9-YL)-3-PIPERAZIN-1-YL-PROPAN-2-OL, BIS TFA SALOR-INT L150053-1EA 1-(4-[2-HYDROXY-3-(1,3,6-TRIBROMO-9H-CARBAZOL-9-YL)PROPYL]PIPERAZINO)-3-(1,3,6-TRIBROMO-9H-CARBAZOL-9-YL)PROPAN-2-OL DIHYDROCHLORIDE 3,6-Dibromocarbazole 1,3,6-TRIBROMO-9-(OXIRAN-2-YLMETHYL)-9H-CARBAZOLE 1-(3,6-DIBROMO-CARBAZOL-9-YL)-3-PYRROLIDIN-1-YL-PROPAN-2-OL 1-(3,6-DIBROMO-9H-CARBAZOL-9-YL)-3-(DIMETHYLAMINO)PROPAN-2-OL Carbazole 3,6-Dibromo-9-ethylcarbazole 3,6-DIBROMO-ALPHA-(1-PIPERAZINYLMETHYL)-9H-CARBAZOLE-9-ETHANOL DIHYDROCHLORIDE 1,3-Dibromopropane 2,3-Dibromopropionic acid 2,2-Bis(bromomethyl)propane-1,3-diol 1,2-Dibromopropane 1-(3,6-DIBROMO-CARBAZOL-9-YL)-3-[4-(4-FLUORO-PHENYL)-PIPERAZIN-1-YL]-PROPAN-2-OL SALOR-INT L144428-1EA 1,3-Dibromo-5,5-dimethylhydantoin meso-2,3-Dibromosuccinic acid

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