ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 4-Iodotoluene

4-Iodotoluene

4-Iodotoluene Basic information
Product Name:4-Iodotoluene
Synonyms:1-IODO-4-METHYLBENZENE;AURORA KA-7367;IODOTOLUENE(4-);4-Iodotouene;4-Iodotoluene,>98%;4-IODOTOLUENE;4-Iodotoluene 98%;4-IODOTOLUENE 99.5%
CAS:624-31-7
MF:C7H7I
MW:218.04
EINECS:210-841-7
Product Categories:alkyl Iodine;Aryl;Building Blocks;C7;Chemical Synthesis;Halogenated Hydrocarbons;Aromatic Hydrocarbons (substituted) & Derivatives;Halogen toluene;Iodine Compounds;Pharmaceutical Intermediate;Organic Building Blocks;Pyridines ,Halogenated Heterocycles;bc0001
Mol File:624-31-7.mol
4-Iodotoluene Structure
4-Iodotoluene Chemical Properties
Melting point 33-35 °C (lit.)
Boiling point 211.5 °C (lit.)
density 1,678 g/cm3
refractive index 1.6155 (estimate)
Fp 194 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Solubility in methanol is almost transparent.
form Crystalline Low Melting Mass
color White to light yellow
Water Solubility insoluble
Sensitive Light Sensitive
BRN 1903637
InChIKeyUDHAWRUAECEBHC-UHFFFAOYSA-N
CAS DataBase Reference624-31-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-iodo-4-methyl-(624-31-7)
EPA Substance Registry SystemBenzene, 1-iodo-4-methyl- (624-31-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/38-36/37/38
Safety Statements 24/25-26
WGK Germany 3
TSCA T
HazardClass IRRITANT
HS Code 29036990
MSDS Information
ProviderLanguage
4-Iodotoluene English
ACROS English
SigmaAldrich English
ALFA English
4-Iodotoluene Usage And Synthesis
Chemical PropertiesWHITE TO LIGHT YELLOW CRYSTALLINE LOW MELTING MASS
Usessuzuki reaction
Uses4-Iodotoluene is used in wide range of medicals industrial applications as well as in pharmaceutical intermediates, polarizing films for Liquid Crystal Display (LCD) chemicals.
Synthesis Reference(s)The Journal of Organic Chemistry, 52, p. 691, 1987 DOI: 10.1021/jo00380a041
Synthesis, p. 572, 1980 DOI: 10.1055/s-1980-29128
General Description4-Iodotoluene undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium. Cobalt-catalyzed coupling of 4-iodotoluene with thiophenols and alkanethiols has been investigated. Palladium/copper-catalyzed Sonogashira cross-coupling reaction of 4-iodotoluene with phenylacetylene has been studied.
Purification MethodsCrystallise 4-iodotoluene from EtOH and.or distil it. [Beilstein 5 IV 840.]
4-Iodotoluene Preparation Products And Raw materials
Preparation ProductsP-TOLUENESULFINIC ACID-->p-Toluoyl chloride-->ar-turmerone-->4,4'-Dimethylbiphenyl-->4-Methyldiphenylamine-->tert-butyl 4-methylphenyl ether-->Di-p-tolylamine-->4-Methylcinnamic acid-->DI-P-TOLYLACETYLENE-->4,N-DIMETHYL-N-METHOXYBENZAMIDE-->P-BUTOXYTOLUENE
Xylene 2,4,6-Trinitrotoluene Benzotrifluoride p-Toluenesulfonic acid o-Xylene Methyl 4-iodobenzoate Acetrizoic acid 4-Iodotoluene Toluene 2-NITRO-4-METHYLSULFONYLTOLUENE m-Xylene 2-Iodotoluene98%,O-IODOTOLUENE 4-Nitrotoluene Tosyl chloride 3-IODOTOLUENE,M-IODOTOLUENE 2-Fluoro-4-iodotoluene 1-IODO-4-ISOPROPYLBENZENE 4-Chlorotoluene
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