[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Basic information

Product Name:	[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
Synonyms:	NiCl2(DPPP)NiCl2(DPPP);1.3-Bis(dipheny phosphine) propane nickel(II)chloride;DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE;NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE;1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride;1,3-Bis-(diphenylphosphino)-propane nickel chloride;Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%;(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride
CAS:	15629-92-2
MF:	C27H26Cl2NiP2
MW:	542.04
EINECS:	605-052-3
Product Categories:	metal-phosphine complexes;Ni;Metal Compounds;Boron, Nitrile, Thio,& TM-Cpds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:	15629-92-2.mol

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Chemical Properties

Melting point	213 °C (dec.)(lit.)
storage temp.	Inert atmosphere,Room Temperature
form	crystal
color	red
Water Solubility	insoluble
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
Exposure limits	NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChIKey	ZBQUMMFUJLOTQC-UHFFFAOYSA-L
CAS DataBase Reference	15629-92-2(CAS DataBase Reference)

Safety Information

MSDS Information

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Usage And Synthesis

Reaction	Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents. Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes. Nickel catalyst used in the borylation of halides and pseudohalides.
Chemical Properties	red to red-brown powder or crystals
Uses	suzuki reaction. Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
Application	Catalyst for: Synthesis of block-copolythiophenes Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids Solid state metathesis polycondensation Polymerization of poly(3-alkoxythiophene)s Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A Transfer condensation polymerization of conjugated polymers [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Preparation Products And Raw materials

Raw materials

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