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(S)-(+)-4-Phenyl-2-oxazolidinone

(S)-(+)-4-Phenyl-2-oxazolidinone Basic information
Product Name:(S)-(+)-4-Phenyl-2-oxazolidinone
Synonyms:(4S)-4-PHENYL-1,3-OXAZOLIDIN-2-ONE;4-S-PHENYL-OXAZOLIDIN-2-ONE;(4S)-PHENYL-2-OXAZOLIDINONE;L-(+)-4-(4S)-PHENYLOXAZOLIDINONE;(S)-PH-OXAZOLIDINONE;SPOX;(S)-(+)-4-PHENYLOXAZOLIDIN-2-ONE;S-4-PHENYL-OXAZOLIDIN-2-ONE
CAS:99395-88-7
MF:C9H9NO2
MW:163.17
EINECS:619-429-5
Product Categories:Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Chiral chemicals;Peptide;Oxazolidinone;Chiral Compounds;chiral;Chiral Reagent;Asymmetric Synthesis;Chiral Building Blocks;99395-88-7
Mol File:99395-88-7.mol
(S)-(+)-4-Phenyl-2-oxazolidinone Structure
(S)-(+)-4-Phenyl-2-oxazolidinone Chemical Properties
Melting point 129-132 °C(lit.)
alpha 49.5 º (c=2, CHCl3)
Boiling point 290.25°C (rough estimate)
density 1.2021 (rough estimate)
refractive index 72 ° (C=1, AcOEt)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka12.05±0.40(Predicted)
form Crystalline Powder
color White
optical activity[α]20/D +48°, c = 2 in chloroform
BRN 131918
InChIKeyQDMNNMIOWVJVLY-MRVPVSSYSA-N
CAS DataBase Reference99395-88-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,F+
Risk Statements 12-36
Safety Statements 24/25-33-26-16-7/9
WGK Germany 3
F 3-9
HS Code 29349990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(S)-(+)-4-Phenyl-2-oxazolidinone Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesVersatile chiral auxiliary for asymmetric synthesis which is easily recycled under mild conditions, thus enhancing its commercial potential. For a recent review, see Aldrichimica Acta .
UsesEzetimibe intermediate
UsesS)-4-Phenyl-2-oxazolidinone is an intermediate for the synthesis and development for cholesterol absorption inhibitor AZD4121.
Oxazolidinone (R)-4,5,5-TRIPHENYL-2-OXAZOLIDINONE N-CROTONYL-(4R,5S)-4-METHYL 5-PHENYL-2-OXAZOLIDINONE (4S)-PHENYL-2-OXAZOLIDINONE 2-AMINO-5-PHENYL-4-OXAZOLIDINONE 3,4α-Dimethyl-5β-phenyl-2-oxazolidinone (S)-(-)-4-ISOPROPYL-5,5-DIPHENYL-2-OXAZOLIDINONE 5-[(2-Propynyloxy)methyl]-3-[2-(trifluoromethyl)phenyl]-2-oxazolidinone N-ACETYL-(4R,5S)-4-METHYL 5-PHENYL-2-OXAZOLIDINONE,N-ACETYL-(4S,5R)-4-METHYL 5-PHENYL-2-OXAZOLIDINONE 5-(Hydroxymethyl)-3-phenyl-2-oxazolidinone Phenylacetone (4S,5S)-4-Methyl-5-phenyl-2-oxazolidinone 5β-tert-Butyl-4β-phenyl-2-oxazolidinone PHENYL VALERATE 5-Phenyl-2-oxazolidinone 3-[4-[[2,5-Dimethoxy-4-[N,N-bis(2-chloroethyl)amino]benzylidene]amino]phenyl]-2-oxazolidinone 1-Phenyl-2-nitropropene 5-(Hydroxymethyl)-3-[3-(trifluoromethyl)phenyl]-2-oxazolidinone
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