ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic rhodium BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE

BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE

BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information
Product Name:BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms:Bis(norbornadiene)rhodium(I)tetrafluoroborate Also avilable as trifluoromethanesulfonate and hexafluorophosphate;BIS(NORBORNADIENE)RHODIUM(I) TETRAFLUOR&;Bis(norbornadiene)rhodium(I)tetrafluoroborate,min.96%;BIS[ETA/-(2,5-NORBORNADIENE)]RHODIUM(I) TERTAFLUOROBORATE;[Rh(ndb)2]BF4;Bis(norbornadiene)rhodium(I) tetrafluoroborate, min. 96%;Bis(norbornadiene)rhodium(I) tetrafluoroborate,94%;Bis(norbornadiene)rhodiuM(I) tetrafluoroborate,96% [Rh(NBD)2]+BF4-
CAS:36620-11-8
MF:C14H8BF4Rh
MW:365.93
EINECS:
Product Categories:Triazoles ,Triazines;Rh;organometallic complex;Tetrafluoroborates;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium;B (Classes of Boron Compounds);Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry
Mol File:36620-11-8.mol
BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Structure
BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties
Melting point 209-211 °C
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Powder
color Red
Water Solubility Fairly soluble in dichloromethane. Insoluble in water.
Sensitive Air & Moisture Sensitive
InChIKeyNMZDXSXETNAOPO-UHFFFAOYSA-M
Safety Information
Hazard Codes F,C
Risk Statements 11-34
Safety Statements 16-45-36/37/39-26
RIDADR 1325
WGK Germany 3
TSCA No
HazardClass 8
PackingGroup II
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
ALFA English
BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis
Chemical Propertiesdark red
UsesBis(norbornadiene)rhodium(I) tetrafluoroborate is used in hydrogenation, Isomerization reactions.
UsesBis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.
ReactionsPrecursor for asymmetric hydrogenation reactions. Reactions of 36620-11-8
BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials
dichlorobis(di-tert-butylphenylphosphine)palladium(II) BIS(DI-TERT-BUTYLPHOSPHINO)METHANE DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Chlorobis(cyclooctene)rhodium(I) dimer Bis[Tris(2-methylphenyl)phosphine]palladium Bis(cyclopentadienyl)zirconium dichloride Bis(dibenzylideneacetone)palladium Dicyclopentadiene diepoxide Bis(triphenylphosphinepalladium) acetate BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Chlorobis(ethylene)rhodium (I) dimer Acetylacetonatobis(ethylene)rhodium(I) DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) methoxy(cyclooctadiene)rhodium(i) dimer BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE EXO-NORBORNEOL BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE 2,5-Norbornadiene
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